147222-99-9

Basic information

• Product Name: Boronic acid, [4-(decyloxy)phenyl]-
• CAS NO: 147222-99-9
• Molecular Formula: C16H27BO3
• Molecular Weight: 278.2
• Mol File: 147222-99-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Boronic acid, [4-(decyloxy)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Boronic acid, [4-(decyloxy)phenyl]-(147222-99-9)
• EPA Substance Registry System: Boronic acid, [4-(decyloxy)phenyl]-(147222-99-9)

Safety Data

• Hazardous Substances Data: 147222-99-9(Hazardous Substances Data)

Upstream product

• 106-41-2 4-bromo-phenol 
• 112-29-8 1-bromo dodecane 
• 121-43-7 Trimethyl borate 
• 30752-20-6 1-bromo-4-decyloxybenzene 

Downstream Products

• 1452822-58-0 (3-(4'-(decyloxy)biphenyl-4-yl)-1,1-difluoroprop-2-ynyl)(p-tolyl)sulfane 
• 1452822-30-8 (Z)-4-(3-(4-sec-butylphenoxy)-2,3,3-trifluoroprop-1-enyl)-4'-(decyloxy)biphenyl 
• 1452822-47-7 4-decyloxy-4'-(2,2,3,3-tetrafluoro-3-tosylpropyl)biphenyl 
• 1452822-50-2 (Z)-(3-(4'-(decyloxy)biphenyl-4-yl)-1,1,2-trifluoroallyl)(p-tolyl)sulfane 
• 179030-93-4 methyl 2,5-bis(4-decyloxyphenyl)benzoate 
• 35108-00-0 4-decyloxyphenol 
• 1391709-17-3 C₃₁H₃₆N₂O₃ 
• 1252055-02-9 1,4-bis(4-decyloxyphenyl)anthraquinone 
• 1048694-18-3 2,4,6-tris(decyloxyphenyl)pyrimidine 

Relevant articles and documents

Ferro-, ferri- and antiferro-electric behaviour in a bent-shaped mesogen

The synthesis of a novel bent-shaped, four-ring thiophene-based chiral liquid crystalline ester derived from 5-(4-n-decyloxyphenyl)thiophene-2- carboxylic acid and (S)-1-methylheptyl 4'-hydroxybiphenyl-4-carboxylate is reported, i.e., (S)-4'-(1-methylheptyloxycarbonyl)biphenyl-4-yl 5-(4-n- decyloxyphenyl)thiophene-2-carboxylate. Optical microscopy, differential scanning calorimetry, miscibility study, and complementary electro-optical and current response studies reveal the existence of the SmA*, SmC* ferroelectric, SmC* ferrielectric, SmC* antiferroelectric and SmI* antiferroelectric phase types. Another mesophase type possibly exists below SmI* antiferroelectric which generates a rapid electro-optic response. Comparison with the analogous three-ring compound, i.e., (S)-4-(1- methylheptyloxycarbonyl)phenyl 5-(4-n-decyloxyphenyl)thiophene-2-carboxylate increases the thermal stability by 95.8 °C and the SmI* antiferroelectric phase is observed in addition.

New pyridine based liquid crystalline esters with different terminal chains

The synthesis, structural and mesomorphic characterization of new pyridine-based methyl esters carrying a n-alkoxy chain or 3,7-Dimethyloctyloxy branched group at terminal have been presented. The liquid crystalline properties of the new pyridine-based calamitic molecules have been investigated by polarized optical microscopy and differential scanning calorimetry. New compounds exhibit enantiotropic smectic A mesophase at a variable mesomorphic range depending on alkoxy chain length and branching at terminal. The presence of a branched terminal group in chiral or racemic form gives rise to a sharply increase in mesomorphic range as well as decrease in crystallization points by preserving mesophase type.

Arylation of chloroanthraquinones by surprisingly facile Suzuki-Miyaura cross-coupling reactions

Chloroanthraquinones were found to undergo facile Suzuki-cross coupling with substituted phenyl boronic acids using a commercial catalyst Pd(PPh 3)4 and with Pd(PPh3)4 prepared in situ from Pd(PPh3)2Cl2 and PPh3.