147641-13-2

Basic information

• Product Name: 2-chlorophenyl nonaflate
• Synonyms: 2-chlorophenyl nonaflate
• CAS NO: 147641-13-2
• Molecular Weight: 410.645
• Mol File: 147641-13-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-chlorophenyl nonaflate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chlorophenyl nonaflate(147641-13-2)
• EPA Substance Registry System: 2-chlorophenyl nonaflate(147641-13-2)

Safety Data

• Hazardous Substances Data: 147641-13-2(Hazardous Substances Data)

Upstream product

• 375-72-4 Nonafluorobutanesulfonyl fluoride 
• 95-57-8 2-monochlorophenol 

Downstream Products

• 18434-12-3 1,2-diphenyl-1H-indole 
• 1205-40-9 N-phenyl-2-chloroaniline 
• 626201-29-4 N-(2-chlorophenyl)-n-hexylamine 
• 95694-54-5 4-(2-chlorophenyl)morpholine 

Relevant articles and documents

Palladium-Catalyzed Amination of Aryl Nonaflates

The first detailed study of the palladium-catalyzed amination of aryl nonaflates is reported. Use of ligands 2-4 and 6 allows for the catalytic amination of electron-rich and -neutral aryl nonaflates with both primary and secondary amines. With use of Xantphos 5, the catalytic amination of a variety of functionalized aryl nonaflates resulted in excellent yields of anilines; even 2-carboxymethyl aryl nonaflate is effectively coupled with a primary alkylamine. Moderate yields were obtained when coupling halo-aryl nonaflates with a variety of amines, where in most cases the aryl nonaflate reacted in preference to the aryl halide. Overall, aryl nonaflates are an effective alternative to triflates in palladium-catalyzed C-N bond-forming processes due to their increased stability under the reaction conditions.