147781-29-1

Basic information

• Product Name: (+/-)-2,2-dimethyl-4r-phenyl-[1,3]dioxan-5c-ylamine
• CAS NO: 147781-29-1
• Molecular Weight: 207.272
• Mol File: 147781-29-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-2,2-dimethyl-4r-phenyl-[1,3]dioxan-5c-ylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-2,2-dimethyl-4r-phenyl-[1,3]dioxan-5c-ylamine(147781-29-1)
• EPA Substance Registry System: (+/-)-2,2-dimethyl-4r-phenyl-[1,3]dioxan-5c-ylamine(147781-29-1)

Safety Data

• Hazardous Substances Data: 147781-29-1(Hazardous Substances Data)

Upstream product

• 4508-82-1 (+/-)-2,2-dimethyl-4r-phenyl-[1,3]dioxan-5c-ylamine 
• 67-64-1 acetone 

Downstream Products

• 4508-83-2 (+/-)-dichloroacetic acid-(2,2-dimethyl-4r-phenyl-[1,3]dioxan-5c-ylamide) 
• 35019-66-0 (4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine 
• 169274-93-5 ((4R,5R)-2,2-Dimethyl-4-phenyl-[1,3]dioxan-5-yl)-[3-phenyl-prop-2-yn-(E)-ylidene]-amine 
• 169274-98-0 (+)-(1R,2R,3'R)-1-Phenyl-2-(1'-phenylhept-1'-in-3'-ylamino)propan-1,3-diol 
• 147722-41-6 (+)-(4R,5R)-2,2-Dimethyl-4-phenyl-N-(3'-phenylprop-2'-in-1'-yliden)-1,3-dioxan-5-amin 

Relevant articles and documents

Tandem radical and non-radical reactions mediated with thiols - A new method of cleavage of allylic amines

Thiyl radical promotes the isomerisation of allylic amines into enamines via two consecutive hydrogen atom abstraction steps, and the subsequent polar addition of the corresponding thiol to the enamine results in the cleavage of the C-N bond via a thioaminal intermediate: this reaction provides a mild, metal-free methodology for the deprotection of allylated primary and secondary amines.