147795-56-0Relevant articles and documents
Phosphine-catalyzed regioselective Michael addition to allenoates
Gandi, Vasudeva Rao,Lu, Yixin
supporting information, p. 16188 - 16190 (2015/11/10)
The first phosphine catalysed Michael addition of arylcyanoacetates to allenoates has been developed, and the β-selective products with a quaternary center were obtained in excellent yields. This unusual regioselectivity may open new opportunities to acce
Metal-free photochemical aromatic perfluoroalkylation of α-cyano arylacetates
Nappi, Manuel,Bergonzini, Giulia,Melchiorre, Paolo
supporting information, p. 4921 - 4925 (2014/05/20)
We report here an operationally simple protocol for the direct aromatic perfluoroalkylation and trifluoromethylation of α-cyano arylacetates. This metal-free approach, which occurs at ambient temperature and under visible-light irradiation, is driven by t
Process for Preparing 2-Arylcarbonyl Compounds, 2-Aryl Esters and 2-Arylnitriles and their Heteroaromatic Analogues
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Page/Page column 5, (2008/12/08)
Process for preparing compounds by cross-coupling of enolizable carbonyl compounds, nitriles or their analogues with substituted aryl or heteroaryl compounds in the presence of a Br?nsted base and of a catalyst or precatalyst containing a.) a transition m