14789-88-9

Basic information

• Product Name: (1-ethyl-butyl)-phenyl ether
• CAS NO: 14789-88-9
• Molecular Weight: 178.274
• Mol File: 14789-88-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1-ethyl-butyl)-phenyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: (1-ethyl-butyl)-phenyl ether(14789-88-9)
• EPA Substance Registry System: (1-ethyl-butyl)-phenyl ether(14789-88-9)

Safety Data

• Hazardous Substances Data: 14789-88-9(Hazardous Substances Data)

Upstream product

• 110-54-3 hexane 
• 122-79-2 Phenyl acetate 
• 592-43-8 2-hexene 
• 108-95-2 phenol 
• 3377-87-5 3-bromohexane 
• 139-02-6 sodium phenoxide 

Relevant articles and documents

Copper Catalyzed sp3 C-H Etherification with Acyl Protected Phenols

A variety of acyl protected phenols AcOAr participate in sp3 C-H etherification of substrates R-H to give alkyl aryl ethers R-OAr employing tBuOOtBu as oxidant with copper(I) β-diketiminato catalysts [CuI]. Although 1°, 2°, and 3° C-H bonds may be functionalized, selectivity studies reveal a preference for the construction of hindered, 3° C-OAr bonds. Mechanistic studies indicate that β-diketiminato copper(II) phenolates [CuII]-OAr play a key role in this C-O bond forming reaction, formed via transesterification of AcOAr with [CuII]-OtBu intermediates generated upon reaction of [CuI] with tBuOOtBu.