148278-86-8

Basic information

• Product Name: N-<(E)-2-chloro-1,2-(4,4'-dimethoxy)diphenylvinylthio>phthalimide
• CAS NO: 148278-86-8
• Molecular Weight: 451.93
• Mol File: 148278-86-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-<(E)-2-chloro-1,2-(4,4'-dimethoxy)diphenylvinylthio>phthalimide(CAS DataBase Reference)
• NIST Chemistry Reference: N-<(E)-2-chloro-1,2-(4,4'-dimethoxy)diphenylvinylthio>phthalimide(148278-86-8)
• EPA Substance Registry System: N-<(E)-2-chloro-1,2-(4,4'-dimethoxy)diphenylvinylthio>phthalimide(148278-86-8)

Safety Data

• Hazardous Substances Data: 148278-86-8(Hazardous Substances Data)

Upstream product

• 54974-07-1 phthalimidesulfenyl chloride 
• 2132-62-9 4,4'-dimethoxydiphenylacetylene 

Relevant articles and documents

Phthalimidesulfenyl chloride; part VII: Synthesis of 2-substituted 3-chlorobenzo[b]thiophenes and related heteroaromatics

Addition of phthalimidesulfenyl chloride (1) to diaryl- or alkyl(aryl) acetylenes affords (E)-β-chlorovinylsulfenamides 3. These species react with aluminum trichloride and other Lewis acids to give benzo[b]thiophenes 6 through an intramolecular electrophilic substitution. The reaction is very simple and seems insensitive to the nature of substituents at the double bond of vinylsulfenamides 3. Following the same strategy the thienothiophene 11 and the condensed thiopyran 12 were also prepared.