148678-86-8Relevant articles and documents
Para-Directed Amination of Electron-Rich Arenes with Bis(2,2,2-trichloroethyl) Azodicarboxylate
Leblanc, Yves,Boudreault, Nicolas
, p. 4268 - 4271 (2007/10/02)
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Synthesis of aromatic amines from electron-rich arenes and bis(2,2,2-trichloroethyl) azodicarboxylate
Zaltsgendler,Leblanc,Bernstein
, p. 2441 - 2444 (2007/10/02)
Electron-rich arenes react with bis(2,2,2-trichloroethyl) azodicarboxylate in 3 M lithium perchlorate-diethylether or acetone solution to produce para-substituted aryl hydrazides in high yields. The corresponding aromatic amines are readily obtained by reducing the hydrazides with zinc in acetic acid.