1509948-51-9Relevant articles and documents
Ambient gold-catalyzed O-vinylation of cyclic 1,3-diketone: A vinyl ether synthesis
Xi, Yumeng,Dong, Boliang,Shi, Xiaodong
, p. 2337 - 2343 (2013)
Gold-catalyzed O-vinylation of cyclic 1,3-diketones has been achieved for the first time, which provides direct access to various vinyl ethers. A catalytic amount of copper triflate was identified as the significant additive in promoting this transformation. Both aromatic and aliphatic alkynes are suitable substrates with good to excellent yields.
Synthesis of cyclic amine boranes through triazole-Gold(I)-catalyzed alkyne hydroboration
Wang, Qiaoyi,Motika, Stephen E.,Akhmedov, Novruz G.,Petersen, Jeffrey L.,Shi, Xiaodong
supporting information, p. 5418 - 5422 (2014/06/09)
The first catalytic alkyne hydroboration of propargyl amine boranecarbonitriles is accomplished with triazole-AuI complexes. While the typical [L-Au]+ species decomposes within minutes upon addition of amine boranecarbonitriles, the
