151158-42-8Relevant articles and documents
A general route for the synthesis of enantiopure indolizidine alkaloids from α-amino acids. Total synthesis of (+)-Monomorine
Angle, Steven R.,Guy Breitenbucher
, p. 3985 - 3988 (2007/10/02)
The ant trail pheromone (+)-Monomorine was synthesized in 9 steps from N-t-BOC-L-alanine ethyl ester. The key step of the synthesis is the conformationally restricted Claisen rearrangement of lactone 9 to pipecolic ester 11.