152203-65-1

Basic information

• Product Name: (4S)-2,2-dimethyl-4-styryl-1,3-dioxolane
• Synonyms: (4S)-2,2-dimethyl-4-styryl-1,3-dioxolane
• CAS NO: 152203-65-1
• Molecular Weight: 204.269
• Mol File: 152203-65-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (4S)-2,2-dimethyl-4-styryl-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: (4S)-2,2-dimethyl-4-styryl-1,3-dioxolane(152203-65-1)
• EPA Substance Registry System: (4S)-2,2-dimethyl-4-styryl-1,3-dioxolane(152203-65-1)

Safety Data

• Hazardous Substances Data: 152203-65-1(Hazardous Substances Data)

Upstream product

• 15186-48-8 2,3-isopropylidene-glyceraldehyde 
• 128990-13-6 (R)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)ethane-1,2-diol 
• 74134-79-5 (4R)-2,2-dimethyl-4-[(2R)-oxiran-2-yl]-1,3-dioxolane 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 140867-27-2 (2R,3R)-1,2-O-methylethylidene-4-phenylbutane-1,2,3-triol 
• 84379-54-4 (R)-2-(benzyloxy)-2-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]ethanol 
• 1100-88-5 benzyltriphenylphosphonium chloride 

Downstream Products

• 152203-66-2 (E)-(S)-4-Phenyl-but-3-ene-1,2-diol 
• 913258-22-7 (S)-1,2-epoxy-4-phenylbutane 
• 41639-83-2 latanoprost acid 
• 118629-73-5 (S)-2-hydroxy-4-phenylbutyl 4-methylbenzenesulfonate 
• 124988-64-3 (S)-4-phenyl-1,2-butanediol 
• 913258-32-9 (Z)-3-hydroxy-2-(hydroxymethyl)-2-methylpropyl 7-((1R,2R,3R,5S)-3,5-dihydroxy-2-((R)-3-hydroxy-5-phenylpentyl)cyclopentyl)hept-5-enoate 
• 145773-22-4 isopropyl (E)-7-{(1R,2R,3R,5S)-3,5-dihydroxy-2-[(R)-3-hydroxy-5-phenylpentyl]cyclopentyl}hept-5-enoate 
• 913258-19-2 (S)-4-phenyl-1-(p-tolylsulfonyloxy)-2-(triethylsiloxy)butane 
• 913258-20-5 (S)-4-phenyl-1-iodo-2-(triethylsiloxy)butane 
• 913258-23-8 (S)-2-hydroxy-1-iodo-4-phenylbutane 
• 913258-21-6 (4S)-4-(2-phenylethyl)-1,3,2-dioxathiolane 2-oxide 
• 157732-87-1 (4S)-2,2-dimethyl-4-(2-phenylethyl)-1,3-dioxolane 
• 851372-04-8 (2R)-2-hydroxy-4-phenylbutyl 4-methylbenzenesulfonate 
• 182950-96-5 (6S)-6-(2-phenylethyl)dihydropyran-2,4⁽³⁾-dione 

Relevant articles and documents

Synthesis of yashabushidiol and its analogues and their cytotoxic activity against cancer cell lines

A total synthesis of yashabushidiol (1a), a linear diarylheptanoid having 1,3- diol system and its analogues has been achieved by alkynylation of 3-hydroxy-5-phenyl pentanal with substituted phenyl acetylenes. All the compounds have shown significant anti

PROCESS FOR PREPARATION OF 13,14-DIHYDRO-PGF2α DERIVATIVES

Invention relates to the process for preparation of 13,14-dihydro-PGF2α derivatives of R or S configuration at carbon atom in omega chain substituted by hydroxyl, represented by formula (I), wherein the meaning of substituents is defined in the description. Compounds (I) are valuable biologically active substances or intermediates thereof. The invention especially relates to the process for preparation of 13,14-dihydro-15(R)-17-substituted-18,19,20-trinor-PGF2α, ie. latanoprost.

Total synthesis of (R)-(+)-kavain via (MeCN)2PdCl 2-catalyzed isomerization of a cis double bond and sonochemical Blaise reaction

From the chiral source 2,3-O-isopropylidene-D-glyceraldehyde 2, the natural product (R)-(+)-kavain 1a was efficiently synthesized in a total yield of 25% via (MeCN)2PdCl2-catalyzed isomerization of the cis double bond of an olefin as the key step and sonochemical Biaise reaction. The chiral center adjacent to the cis double bond was retained without protection of the free allylic hydroxy during the isomerization process. Georg Thieme Verlag Stuttgart.