152453-71-9

Basic information

• Product Name: (1'S,4R)-4-(3',3'-bisethylthio-1'-p-methoxybenzyloxypropyl)-2,2-dimethyl-1,3-dioxolane
• Synonyms: (1'S,4R)-4-(3',3'-bisethylthio-1'-p-methoxybenzyloxypropyl)-2,2-dimethyl-1,3-dioxolane
• CAS NO: 152453-71-9
• Molecular Weight: 400.604
• Mol File: 152453-71-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (1'S,4R)-4-(3',3'-bisethylthio-1'-p-methoxybenzyloxypropyl)-2,2-dimethyl-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: (1'S,4R)-4-(3',3'-bisethylthio-1'-p-methoxybenzyloxypropyl)-2,2-dimethyl-1,3-dioxolane(152453-71-9)
• EPA Substance Registry System: (1'S,4R)-4-(3',3'-bisethylthio-1'-p-methoxybenzyloxypropyl)-2,2-dimethyl-1,3-dioxolane(152453-71-9)

Safety Data

• Hazardous Substances Data: 152453-71-9(Hazardous Substances Data)

Upstream product

• 67320-20-1 1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-3,3-bis-ethylsulfanyl-propan-1-ol 
• 2746-25-0 p-Methoxybenzyl bromide 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 152453-82-2 <3S-<3α(1R*,2R*,3S*,5R*,6E),4β(1E,3E)>>-1-<(1,1-dimethylethyl)dimethylsilyl>-4-<5-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-2-methyl-1,3-pentadienyl>-3-<3-<<(1,1-diphenylethyl)dimethylsilyl>oxy>-1-hydroxy-7-iodo-5-<(4-methoxyphenyl)methoxy>-2-methyl..>. 
• 152453-83-3 <4R-<4α(2E,4E),4aβ,7α(2S*,3E),8β,8aβ>>-1H-imidazole-1-carboxylic acid 5--3-butenyl>-4a,8-dimethyl-2,5-dioxo-2H,5H-pyrano<3,4-e>-1,3-oxazin-4-yl>-4-methyl-2,4-pentadienyl ester 
• 152453-80-0 <2R-(2R*,3R*,5S*,6E)>-3-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-7-iodo-5-<(4-methoxyphenyl)methoxy>-2-methyl-6-heptenoic acid (S)-2-pyridinyl ester 
• 152453-75-3 2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid methyl ester 
• 152453-77-5 2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptaldonic acid 
• 166186-04-5 2,4-dideoxy-3-O-<(1,1-dimethylethyl)diphenylsilyl>-5-O-<(4-methoxyphenyl)methyl>-2-methyl-6,7-O-(1-methylethylidene)-D-allo-heptose 
• 152453-74-2 <4R-<4R*>>-<<1-<2-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-<(4-methoxyphenyl)methoxy>ethyl>-2-methyl-3-butenyl>oxy>(1,1-dimethylethyl)diphenylsilane 
• 152453-78-6 <2R-(2R*,3R*,5S*,6E)>-3-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-7-iodo-5-<(4-methoxyphenyl)methoxy>-2-methyl-6-heptenoic acid methyl ester 
• 166186-05-6 (2R,3R,5S,6R)-3-(tert-Butyl-diphenyl-silanyloxy)-6,7-dihydroxy-5-(4-methoxy-benzyloxy)-2-methyl-heptanoic acid methyl ester 
• 152453-79-7 <2R-(2R*,3R*,5S*,6E)>-3-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-7-iodo-5-<(4-methoxyphenyl)methoxy>-2-methyl-6-heptenoic acid 
• 152453-76-4 3,5-dideoxy-4-O-<(1,1-dimethylethyl)diphenylsilyl>-2-O-<(4-methoxyphenyl)methyl>-5-methyl-L-ribo-hexuronic acid methyl ester 
• 152453-73-1 <4R-<4R*<αR*(S*),γS*>>>-γ-<(4-methoxyphenyl)methoxy>-2,2-dimethyl-α-(1-methyl-2-propenyl)-1,3-dioxolane-4-propanol 
• 208713-61-5 Toluene-4-sulfonic acid (2R,3S)-5,5-bis-ethylsulfanyl-2-hydroxy-3-(4-methoxy-benzyloxy)-pentyl ester 
• 208713-50-2 (2R,3S)-5,5-Bis-ethylsulfanyl-3-(4-methoxy-benzyloxy)-pentan-2-ol 

Relevant articles and documents

First total synthesis of mueggelone

All the four possible stereoisomers of mueggelone, an inhibitor of fish development, were efficiently synthesized in a stereoselective manner starting from D-arabinose, and the absolute configuration was determined to be 9R,12S, 13S. (C) 2000 Elsevier Science Ltd.

First total synthesis and determination of the absolute configuration of mueggelone

All the four possible stereoisomers of mueggelone, an inhibitor of fish development, were efficiently synthesized in a stereoselective manner starting from D-arabinose, and the absolute configuration was determined to be 9R, 12S, 13S.

Total synthesis of the macrolide antitumor antibiotic lankacidin C

The first total synthesis of natural (-)-lankacidin C (1) has been achieved by a convergent, enantioselective sequence starting from D-arabinose and L-aspartic acid, proceeding through the tricyclic carbamate 15 as an advanced relay intermediate. Specific