15290-25-2

Basic information

• Product Name: 3-Trimethylsilanylaniline
• Synonyms: 3-Trimethylsilanylaniline
• CAS NO: 15290-25-2
• Molecular Formula: C₉H₁₅NSi
• Molecular Weight: 165.3076
• Mol File: 15290-25-2.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 111 °C(Press: 10 Torr)
• Appearance: /
• Density: 0.947 g/cm3
• PKA: 4.69±0.10(Predicted)
• CAS DataBase Reference: 3-Trimethylsilanylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Trimethylsilanylaniline(15290-25-2)
• EPA Substance Registry System: 3-Trimethylsilanylaniline(15290-25-2)

Safety Data

• Hazardous Substances Data: 15290-25-2(Hazardous Substances Data)

Upstream product

• 15290-24-1 3-nitro-1-(trimethylsilyl)benzene 
• 17876-71-0 me3Si(ph-3-CONH₂) 
• 15288-53-6 o-(trimethylsilyl)phenol 

Downstream Products

• 18663-01-9 1-(3-trimethylsilanyl-phenylazo)-[2]naphthol 
• 15290-26-3 3'-(trimethylsilyl)acetanilide 
• 125973-66-2 methyl 4-<<3-(trimethylsilyl)phenyl>carbamoyl>benzoate 
• 125973-48-0 4-<<3-(trimethylsilyl)phenyl>carbamoyl>benzoic acid 
• 18663-01-9 (CH₃)3Si(C₆H₄NNC₁₀H₆OH) 
• 1449294-74-9 3-(3-(trimethylsilyl)phenyl)quinazoline-2,4(1H,3H)-dione 

Relevant articles and documents

One-Pot Generation of Benzynes from Phenols: Formation of Primary Anilines by the Deoxyamination of Phenols

Benzynes were selectively generated in situ from phenols and trapped regioselectively with potassium hexamethyldisilazide to form primary anilines following acidic workup. The direct conversion of a phenolic hydroxyl group into a free amino group is a useful method for the preparation of primary aryl amines that are hard to synthesize by using coupling reactions involving phenol derivatives with ammonia. Whereas reactions of ortho- and meta-substituted phenols produced meta-substituted anilines exclusively, those of para-substituted phenols provided ortho-silylanilines.