153711-74-1

Basic information

• Product Name: tert-Butyl-diphenyl-vinyloxy-silane
• Synonyms: tert-Butyl-diphenyl-vinyloxy-silane
• CAS NO: 153711-74-1
• Molecular Weight: 282.458
• Mol File: 153711-74-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: tert-Butyl-diphenyl-vinyloxy-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-diphenyl-vinyloxy-silane(153711-74-1)
• EPA Substance Registry System: tert-Butyl-diphenyl-vinyloxy-silane(153711-74-1)

Safety Data

• Hazardous Substances Data: 153711-74-1(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 2973-86-6 lithium thiophenoxide 
• 167865-70-5 tert-Butyl-oxiranyl-diphenyl-silane 
• 96-47-9 2-methyltetrahydrofuran 
• 1415455-17-2 C₁₃H₂₄O₂ 

Relevant articles and documents

Regio- and stereospecific cleavage of α,β-epoxysilanes with lithium phenylsulfide

Trimethyl- or dimethylphenylsilylepoxides react with lithium phenylsulfide to give regio- and stereodefined vinyl sulfides resulting from α-ring opening and Peterson elimination. When the epoxide bears the bulky tert-butyldiphenylsilyl group the reaction

A base-promoted deprotection of 1,3-dioxolanes to ketones

An effective deprotection methodology of dioxolanes was developed, affording moderate to excellent yield via a LTMP-promoted reaction in THF, which displays admirable chemoselectivity in the presence of dimethylketal, 1,3-dioxane, 1,3-dithiane, or other acid-sensitive protective groups.