1542154-94-8

Basic information

• Product Name: [(4'-(4-methoxyphenyl)-2,2':6',''-terpyridine)IrCl₃]
• CAS NO: 1542154-94-8
• Molecular Weight: 637.975
• Mol File: 1542154-94-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(4'-(4-methoxyphenyl)-2,2':6',''-terpyridine)IrCl₃](CAS DataBase Reference)
• NIST Chemistry Reference: [(4'-(4-methoxyphenyl)-2,2':6',''-terpyridine)IrCl₃](1542154-94-8)
• EPA Substance Registry System: [(4'-(4-methoxyphenyl)-2,2':6',''-terpyridine)IrCl₃](1542154-94-8)

Safety Data

• Hazardous Substances Data: 1542154-94-8(Hazardous Substances Data)

Upstream product

• 181866-50-2 4′-methoxy-2,2′:6′,2′′-terpyridine 

Relevant articles and documents

Selective DNA purine base photooxidation by bis-terdentate iridium(III) polypyridyl and cyclometalated complexes

Two bis-terdentate iridium(III) complexes with polypyridyl and cyclometalated ligands have been prepared and characterized. Their spectroscopic and electrochemical properties have been studied, and a photophysical scheme addressing their properties is proposed. Different types of excited states have been considered to account for the deactivation processes in each complex. Interestingly, in the presence of mono- or polynucleotides, a photoinduced electron-transfer process from a DNA purine base (i.e., guanine or adenine) to the excited complex is shown through luminescence quenching experiments. For the first time, this work reports evidence for selective DNA purine bases oxidation by excited iridium(III) bis-terdentate complexes.