1542275-72-8

Basic information

• Product Name: 4-(1-methyl-1H-benzimidazol-2-yl)-N,N-diphenylbenzenamine
• Synonyms: 4-(1-methyl-1H-benzimidazol-2-yl)-N,N-diphenylbenzenamine
• CAS NO: 1542275-72-8
• Molecular Weight: 375.473
• Mol File: 1542275-72-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(1-methyl-1H-benzimidazol-2-yl)-N,N-diphenylbenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(1-methyl-1H-benzimidazol-2-yl)-N,N-diphenylbenzenamine(1542275-72-8)
• EPA Substance Registry System: 4-(1-methyl-1H-benzimidazol-2-yl)-N,N-diphenylbenzenamine(1542275-72-8)

Safety Data

• Hazardous Substances Data: 1542275-72-8(Hazardous Substances Data)

Upstream product

• 1632-83-3 1-Methylbenzimidazole 
• 4316-51-2 N,N-diphenyl-4-methoxyaniline 
• 603-34-9 N,N-diphenylaminobenzene 
• 4181-05-9 4-(diphenylamino)benzaldehyde 
• 95-54-5 1,2-diamino-benzene 
• 1332836-93-7 2-(4-(N,N-diphenylamino)phenyl)-1,3-benzimidazole 
• 74-88-4 methyl iodide 

Downstream Products

• 1542678-43-2 Ir(4-(1-methyl-1H-benzimidazol-2-yl)-N,N-diphenylbenzenamine-H)₃ 

Relevant articles and documents

Nickel-Catalyzed Heteroarenes Cross Coupling via Tandem C-H/C-O Activation

Inert aryl methyl ethers as coupling components via C-O activation have been established with a Ni catalyst for C-H activation of heteroarene. The key to simultaneous C-H/C-O bond activation is the use of sterically demanding o-tolylMgBr. The protocol is effective for a wide scope of substrates including naphthyl methyl ethers, anisoles, and a variety of other heteroarene derivatives. Detailed mechanistic studies indicated that the C-O cleavage is assisted via synergistic effect of nickel and Grignard reagent in this C-H/C-O reaction, which is supported by DFT calculation. At this stage, single-electron transfer can be ruled out as a main operative process for this tandem strategy.