155444-61-4

Basic information

• Product Name: phenyl β-(trifluoromethyl)vinyl sulfide
• Synonyms: phenyl β-(trifluoromethyl)vinyl sulfide
• CAS NO: 155444-61-4
• Molecular Weight: 204.216
• Mol File: 155444-61-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 244.1±40.0 °C(Predicted)
• Density: 1.25±0.1 g/cm3(Predicted)
• CAS DataBase Reference: phenyl β-(trifluoromethyl)vinyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl β-(trifluoromethyl)vinyl sulfide(155444-61-4)
• EPA Substance Registry System: phenyl β-(trifluoromethyl)vinyl sulfide(155444-61-4)

Safety Data

• Hazardous Substances Data: 155444-61-4(Hazardous Substances Data)

Upstream product

• 34509-09-6 1,1,1-trifluoro-3-(phenylthio)propan-2-one 
• 100-68-5 methyl-phenyl-thioether 
• 1514-82-5 2-bromo-3,3,3-trifluoropropene 
• 108-98-5 thiophenol 
• 139732-10-8 3,3,3-trifluoro-1-(phenylthio)propyl acetate 
• 762-72-1 allyl-trimethyl-silane 
• 88790-05-0 Methanesulfonic acid 2,2,2-trifluoro-1-phenylsulfanylmethyl-ethyl ester 
• 99728-16-2 (Z)-1-chloro-3,3,3-trifluoro-1-propene 
• 88790-04-9 2-hydroxy-3,3,3-trifluoropropyl phenyl sulfide 
• 139732-09-5 phenyl 3,3,3-trifluoropropyl sulfoxide 
• 102687-64-9 Phenyl 3,3,3-trifluoropropyl sulfide 

Downstream Products

• 1226574-99-7 (E)-diphenyl-β-(trifluoromethyl)vinylsulfonium trifluoromethanesulfonate 
• 1228046-56-7 (β-trifluoromethyl)vinyl diphenylsulfonium trifluoromethanesulfonate 
• 102687-77-4 2-(2-Benzenesulfonyl-3-hydroxy-3-phenyl-1-trifluoromethyl-propyl)-malonic acid diethyl ester 
• 102687-71-8 2-Acetylamino-2-(1-benzenesulfonylmethyl-2,2,2-trifluoro-ethyl)-malonic acid diethyl ester 
• 102687-79-6 2-Benzenesulfonyl-3-benzylamino-4,4,4-trifluoro-1-phenyl-butan-1-ol 
• 102687-72-9 (1-Benzenesulfonylmethyl-2,2,2-trifluoro-ethyl)-benzyl-amine 
• 120226-15-5 methyl 3-trifluoromethyl-4-phenylsulfonylbutanoate 
• 120226-10-0 (Z)-1-phenylsulfonyl-3,3,3-trifluoropropene 
• 102719-25-5 2-(1-Benzenesulfonylmethyl-2,2,2-trifluoro-ethyl)-malonic acid diethyl ester 
• 102687-67-2 4-phenylsulfonyl-3-trifluoromethyl-1-phenylbutan-1-one 
• 177272-50-3 1-Bromo-1-phenylsulfanyl-3,3,3-trifluoroprop-1-ene 
• 88790-06-1 (1,2-Dibromo-3,3,3-trifluoro-propylsulfanyl)-benzene 
• 102687-63-8 (E)-((3,3,3-trifluoroprop-1-en-1-yl)sulfonyl)benzene 

Relevant articles and documents

Synthesis of 2-aryl-3-fluoro-5-silylthiophenes via a cascade reactive sequence

2-Aryl-3-fluoro-5-silylthiophenes were readily prepared only in two steps from 2-bromo-3,3,3-trifluoropropene in good yields. These transformations include the first successful SN2′-type reaction of 2-bromo-3,3,3-trifluoropropene and benzylthio

Electrolytic Reactions of Fluoro Organic Compounds. 11. Anodic Preparation and Synthetic Applications of β-Trifluoromethylated O,S-Acetals

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2-HALOVINYL ARYL SULFONES: NEW COUPLING REAGENTS FOR CARBOXAMIDE FORMATION

E-2-Chlorovinyl p-nitrophenyl sulfone 6 and 2-bromo-2-trifluoromethylvinyl phenyl sulfone 7a reacted with carboxylic acids in the presence of a molar equiv of Et3N affording the corresponding 2-acyloxyvinyl sulfones 8, 11, 17, 18, 22, 25, 28 and 29.The latter, on treatment with amines, gave amides 9, 13, 19, 23 and 26 and peptides 30 and 32.These reagents 6 and 7a were also used for the formation of N-methylanilides 13d, 13e, 19d, 23 and 26.Particularly, 6 was successfully used for synthesis of a macrocyclic lactam 23 involving a N-methylanilide moiety.The amidation reac tions proceeded under essentially neutral conditions.Therefore, base-sensitive β-hydroxycarboxy-N-methylanilides such as 26, whose structural unit was involved in maytansine 5, could be prepared by the present method.The reagent 6 was also effective for the preparation of peptides such as Val-N-MeVal derivatives (e.g.32), which were difficult to prepare by other methods.