155773-71-0 Usage
Description
NI(II)-1,4,8,11,15,18,22,25-OCTABUTOXY-PHTHALOCYANINE is a complex chemical compound that features a central nickel atom (NI) coordinated with 1,4,8,11,15,18,22,25-octabutoxyphthalocyanine. NI(II)-1,4,8,11,15,18,22,25-OCTABUTOXYPHTHALOCYANINE is known for its stability and solubility, which are provided by the octabutoxyphthalocyanine ligand. Its unique properties and efficiency in absorbing and transferring light make it a valuable asset in various chemical and biomedical applications.
Uses
Used in Organic Electronic Devices:
NI(II)-1,4,8,11,15,18,22,25-OCTABUTOXY-PHTHALOCYANINE is utilized as a key component in organic electronic devices due to its ability to efficiently absorb and transfer light, enhancing the performance and efficiency of these devices.
Used in Photodynamic Therapy (PDT) as a Photosensitizer:
In the medical field, NI(II)-1,4,8,11,15,18,22,25-OCTABUTOXY-PHTHALOCYANINE serves as a photosensitizer for photodynamic therapy. It plays a crucial role in the treatment process by absorbing light and generating reactive oxygen species, which are effective in eliminating cancer cells.
Used in Organic Photovoltaic Cells:
NI(II)-1,4,8,11,15,18,22,25-OCTABUTOXYPHTHALOCYANINE is also employed in organic photovoltaic cells, where it contributes to the conversion of light into electricity. Its light-absorbing and transferring capabilities make it a suitable material for improving the efficiency of solar cells.
Used in Chemical and Biomedical Research:
NI(II)-1,4,8,11,15,18,22,25-OCTABUTOXY-PHTHALOCYANINE is a valuable tool in modern chemical and biomedical research, where it is used to explore new applications and improve existing technologies, taking advantage of its unique properties and light manipulation capabilities.
Check Digit Verification of cas no
The CAS Registry Mumber 155773-71-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,5,7,7 and 3 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 155773-71:
(8*1)+(7*5)+(6*5)+(5*7)+(4*7)+(3*3)+(2*7)+(1*1)=160
160 % 10 = 0
So 155773-71-0 is a valid CAS Registry Number.
InChI:InChI=1/C64H80N8O8.Ni/c1-9-17-33-73-41-25-26-42(74-34-18-10-2)50-49(41)57-65-58(50)70-60-53-45(77-37-21-13-5)29-30-46(78-38-22-14-6)54(53)62(67-60)72-64-56-48(80-40-24-16-8)32-31-47(79-39-23-15-7)55(56)63(68-64)71-61-52-44(76-36-20-12-4)28-27-43(75-35-19-11-3)51(52)59(66-61)69-57;/h25-32H,9-24,33-40H2,1-8H3;/q-2;+2
155773-71-0Relevant articles and documents
Photophysics of octabutoxy phthalocyaninato-Ni(II) in toluene: Ultrafast experiments and DFT/TDDFT studies
Gunaratne, Tissa C.,Gusev, Alexey V.,Peng, Xinzhan,Rosa, Angela,Ricciardi, Giampaolo,Baerends, Evert Jan,Rizzoli, Corrado,Kenney, Malcolm E.,Rodgers, Michael A. J.
, p. 2078 - 2089 (2005)
Reported herein is a combination of experimental and DFT/TDDFT theoretical investigations of the ground and excited states of 1,4,8,11,15,18,22,25- Octabutoxyphthalocyaninato-nickel(II), NiPc(BuO)8, and the dynamics of its deactivation after excitation into the S1(π,π*) state in toluene solution. According to X-ray crystallographic analysis NiPc(BuO)8 has a highly saddled structure in the solid state. However, DFT studies suggest that in solution the complex is likely to flap from one D2d-saddled conformation to the opposite one through a D 4h-planar structure. The spectral and kinetic changes for the complex in toluene are understood in terms of the 730 nm excitation light generating a primarily excited S1 (π,π*) state that transforms initially into a vibrationally hot 3(dz2,dx2-y2 state. Cooling to the zeroth state is complete after ca. 8 ps. The cold (d,d) state converted to its daughter state, the 3LMCT (πd x2-y2), which itself decays to the ground state with a lifetime of 640 ps. The proposed deactivation mechanism applies to the D2d- saddled and the D4h-planar structure as well. The results presented here for NiPc(BuO)8 suggest that in nickel phthalocyanines the 1,3LMCT (π,dx2-y2) states may provide effective routes for radiationless deactivation of the 1,3(π,π*) states.
