15619-54-2

Basic information

• Product Name: Peroxide, cyclohexyl 1,1-dimethylethyl
• CAS NO: 15619-54-2
• Molecular Formula: C10H20O2
• Molecular Weight: 172.268
• Mol File: 15619-54-2.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Peroxide, cyclohexyl 1,1-dimethylethyl(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, cyclohexyl 1,1-dimethylethyl(15619-54-2)
• EPA Substance Registry System: Peroxide, cyclohexyl 1,1-dimethylethyl(15619-54-2)

Safety Data

• Hazardous Substances Data: 15619-54-2(Hazardous Substances Data)

Upstream product

• 75-91-2 tert.-butylhydroperoxide 
• 110-82-7 cyclohexane 
• 2372-21-6 OO-tert-butyl O-isopropyl monoperoxycarbonate 
• 108-85-0 1-bromocyclohexane 
• 110-83-8 cyclohexene 
• 90466-74-3 C₁₀H₁₉O₂ 
• 187939-66-8 1-tert-butylperoxy-3,3-dimethyl-1H-1,2-benziodoxole 
• 56375-24-7 1-Bromo-2-tert-butylperoxy-cyclohexane 
• 14976-54-6 di-tert-butoxydiazene 

Relevant articles and documents

Highly selective cycloalkane oxidation in water with ruthenium nanoparticles

Ruthenium(0) nanospecies, with small sizes of approximately 1.75 nm, proved to be active, selective, and retrievable nanocatalysts for the oxidation of various cycloalkanes in neat water, using tert-butylhydroperoxide as an oxidant and at room temperature. Relevant conversions and selectivities (up to 97 %) were achieved towards the major formation of the ketone product, which constitutes a high-value-added intermediate for polymer or fine chemistry. The lifetime of the catalyst has been checked over several runs, with no significant loss of activity and selectivity. Kinetic and mechanistic investigations proved that radical species are involved in the oxidation process. A literature comparison showed the relevance and the usefulness of the present ruthenium nanocatalytic system in a benign reaction context. Active, selective, and retrievable! A sustainable oxidation process of cycloalkanes to the ketones with an easy-to-handle and reusable catalyst, in neat water, and under ambient conditions is described. The active catalyst is a ruthenium(0) nanospecies. t-BHP=tert-butylhydroperoxide.

Selective oxidation of cyclohexane to cyclohexanol catalyzed by a μ-hydroxo diiron(II) complex and tert-butylhydroperoxide

A new μ-hydroxo diiron(II) complex [Fe2L(OH)]3+ obtained with a dinucleating macrocyclic ligand catalyzes the selective oxidation of cyclohexane into cyclohexanol (≈85%) using the controlled addition of tert-butylhydroperoxide.

Ruthenium colloids: A new catalyst for alkane oxidation by tBHP in a biphasic water-organic phase system

Efficient and highly selective conversion of cyclooctane into cyclooctanone is obtained under pure biphasic conditions through t-butylhydroperoxide activation by the in situ formation of colloidal ruthenium species arising from RuCl3, 3H2O. Model extension experiments to other cycloalkanes are also discussed.