15763-61-8

Basic information

• Product Name: t-butyl-4 cyclohexanecarboxaldehyde cis
• Synonyms: t-butyl-4 cyclohexanecarboxaldehyde cis
• CAS NO: 15763-61-8
• Molecular Weight: 168.279
• Mol File: 15763-61-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: t-butyl-4 cyclohexanecarboxaldehyde cis(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl-4 cyclohexanecarboxaldehyde cis(15763-61-8)
• EPA Substance Registry System: t-butyl-4 cyclohexanecarboxaldehyde cis(15763-61-8)

Safety Data

• Hazardous Substances Data: 15763-61-8(Hazardous Substances Data)

Upstream product

• 13004-06-3 cis-(4-tert-butylcyclohexyl)methanol 
• 18881-26-0 (3r,6r)-6-(tert-butyl)-1-oxaspiro[2.5]octane 
• 98-73-7 4-(1,1-dimethylethyl)benzoic acid 
• 7787-78-2 6-tert-Butyl-1-oxa-spiro[2.5]octane 
• 201230-82-2 carbon monoxide 
• 2228-98-0 4-tert-butylcylohexene 
• 943-28-2 cis-4-t-butylcyclohexanecarboxylic acid 
• 13294-73-0 1-tert-butyl-4-methylenecyclohexane 
• 98-53-3 4-tercbutyl-cyclohexanone 

Downstream Products

• 1083335-57-2 C₂₀H₃₀O 

Relevant articles and documents

Axial and equatorial cyclohexylacyl and tetrahydropyranyl-2-acyl radicals. An experimental and theoretical study

(Chemical Equation Presented) Axial and equatorial cyclohexylacyl and tetrahydropyranyl-2-acyl radicals gave distinct EPR spectra thanks to surprisingly large β-hydrogen atom hyperfine splittings that enabled them to be characterized and monitored. DFT computations indicated that the axial species (X = CH2) had a higher barrier to rotation about the (O)Cα-Cα bond. The computed difference ΔH° for the axial and equatorial radicals (R = H, X = CH2) was 0.8 kcal mol -1.

THE STEREOCHEMISTRY OF METAL CATALYSED HYDROGEN CYANIDE ADDITION TO ALKENES

Reaction of both terminal and cyclic alkenes have been shown to occur in a stereospecifically cis-manner with deuterium cyanide when a catalyst system based on Pd(DIOP)2 was used.Reactions of cyclohexene give only the products of equatorial cyanide incorporation.