1609547-62-7

Basic information

• Product Name: C₁₆H₁₈O₄
• Synonyms: C₁₆H₁₈O₄
• CAS NO: 1609547-62-7
• Molecular Weight: 274.317
• Mol File: 1609547-62-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₁₈O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₁₈O₄(1609547-62-7)
• EPA Substance Registry System: C₁₆H₁₈O₄(1609547-62-7)

Safety Data

• Hazardous Substances Data: 1609547-62-7(Hazardous Substances Data)

Upstream product

• 24680-50-0 4-methoxy-trans-cinnamaldehyde 
• 141-97-9 ethyl acetoacetate 

Downstream Products

• 1609547-46-7 ethyl (E)-4-(4-methoxystyryl)-2-methyl-4,5-dihydrofuran-3-carboxylate 
• 2004-63-9 ethyl 6‐(4‐methoxyphenyl)‐2‐methylnicotinate 

Relevant articles and documents

Visible-light-promoted iminyl-radical formation from Acyl oximes: A unified approach to pyridines, quinolines, and phenanthridines

A unified strategy involving visible-light-induced iminyl-radical formation has been established for the construction of pyridines, quinolines, and phenanthridines from acyl oximes. With fac-[Ir(ppy)3] as a photoredox catalyst, the acyl oximes were converted by 1 e- reduction into iminyl radical intermediates, which then underwent intramolecular homolytic aromatic substitution (HAS) to give the N-containing arenes. These reactions proceeded with a broad range of substrates at room temperature in high yield. This strategy of visible-light-induced iminyl-radical formation was successfully applied to a five-step concise synthesis of benzo[c]phenanthridine alkaloids.