161123-34-8

Basic information

• Product Name: (S_S,S)-2-(p-toluenesulfinylamino)-4-methylpentanenitrile
• Synonyms: (S_S,S)-2-(p-toluenesulfinylamino)-4-methylpentanenitrile
• CAS NO: 161123-34-8
• Molecular Weight: 250.365
• Mol File: 161123-34-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S_S,S)-2-(p-toluenesulfinylamino)-4-methylpentanenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (S_S,S)-2-(p-toluenesulfinylamino)-4-methylpentanenitrile(161123-34-8)
• EPA Substance Registry System: (S_S,S)-2-(p-toluenesulfinylamino)-4-methylpentanenitrile(161123-34-8)

Safety Data

• Hazardous Substances Data: 161123-34-8(Hazardous Substances Data)

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 188447-85-0 (S)-(+)-N-(3-methylbutylidene)-p-toluenesulfinamide 
• 5804-85-3 diethylaluminium cyanide 

Downstream Products

• 61-90-5 L-leucine 

Relevant articles and documents

Highly diastereoselective strecker reaction of enolizable aliphatic sulfinimines

The reaction of chiral sulfinimines 1c-g derived from aliphatic aldehydes with TMSCN in the presence of CsF gave α-amino nitriles in high diastereoselectivity and yield. α,β-Diamino acid derivatives were also obtained in high diastereoselectivity from the reaction of 2-aziridinesulfinimines 1h and 1i followed by ring-opening of the products with thiophenol. The presence ofhydrogen of hydrogen at the α-position of the C=N double bond is crucial in this TMSCN addition reaction.