1622081-15-5

Basic information

• Product Name: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylseleno-α-D-glucopyranoside
• Synonyms: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylseleno-α-D-glucopyranoside
• CAS NO: 1622081-15-5
• Molecular Weight: 459.355
• Mol File: 1622081-15-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylseleno-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylseleno-α-D-glucopyranoside(1622081-15-5)
• EPA Substance Registry System: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylseleno-α-D-glucopyranoside(1622081-15-5)

Safety Data

• Hazardous Substances Data: 1622081-15-5(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 7404-32-2 methyl 2,3,4-tri-O-acetyl-6-bromo-6-deoxy-α-D-glucopyranoside 

Relevant articles and documents

Useful approach to the synthesis of aryl thio- and selenoglycosides in the presence of rongalite

A simple, mild, and cost effective methodology has been developed for the synthesis of aryl thio-and selenoglycosides from glycosyl halides and diaryl dichalcogenides. Diaryl dichalcogenides undergo reductive cleavage in the presence of rongalite (HOCH2SO2Na) to generate a chalcogenide anion in situ followed by reaction with glycosyl halides to furnish the corresponding aryl thio- and selenoglycosides in excellent yields. Using this protocol, synthesis of 4-methyl-7-thioumbelliferyl-β-d-cellobioside (MUS-CB), a fluorescent non-hydrolyzable substrate analogue for cellulases has been achieved.