16294-32-9

Basic information

• Product Name: 1,5-dimethoxyanthracene
• Synonyms: 1,5-dimethoxyanthracene
• CAS NO: 16294-32-9
• Molecular Formula: C₁₆H₁₄O₂
• Molecular Weight: 238.28116
• Mol File: 16294-32-9.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,5-dimethoxyanthracene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-dimethoxyanthracene(16294-32-9)
• EPA Substance Registry System: 1,5-dimethoxyanthracene(16294-32-9)

Safety Data

• Hazardous Substances Data: 16294-32-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 809, 1981 DOI: 10.1021/jo00317a034

Upstream product

• 67-56-1 methanol 
• 607-62-5 anthracene-1,5-diol 
• 75829-91-3 1,5-dimethoxy-9,10-dihydro-anthracene 
• 512-56-1 trimethyl phosphite 
• 79015-49-9 anthracene-1,5-diamine 
• 6448-90-4 1,5-dimethoxy-anthraquinone 
• 75829-87-7 1,5-dimethoxy-9,10-dihydro-9,10-anthracenediol 
• 121564-40-7 1,5-bis(methoxymethoxy)-9,10-anthraquinone 
• 117-12-4 1,5-dihydroxyanthraquinone 
• 82-46-2 1,5-Dichloroanthraquinone 

Downstream Products

• 100466-92-0 9,10-Dihydro-3,13-dimethoxy-9,10-<1',2'>benzenoanthracen-1,4-diol 

Relevant articles and documents

COMPOUNDS AND METHODS OF TREATING RNA-MEDIATED DISEASES

The present invention provides compounds, compositions thereof, and methods of using the same.

C-glycosylanthraquinone synthesis: Total synthesis of vineomycinone B2 methyl ester

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ESR Spectroscopic Detection of Intramolecular Interactions in Radical Cations of Poly(α-methoxy)triptycenes

-Cycloaddition of 1,4-benzoquinone to the di- and tetra(α-methoxy)anthracenes 11 yields the diketones 12 which undergo an acid-catalyzed rearrangement to the triptycene hydroquinones 13.Methylation of 13 affords the poly(α-methoxy)triptycenes 4.Aluminium chloride in nitromethane oxidizes the triptycenes 4 to the radical cations 4+* having one 1,4-dialkoxybenzene ring (4b+*, 4c+*, 4e+*) or two (4a+*) or three (4d+*), respectively, of such potential radical centers.The protons of the radical center give rise to hyperfine splittings which are very similar to those found in the ESR spectra of simple cis-1,4-dialkoxybenzene radical cations.The other aromatic protons, but not the bridgehead protons, exhibit a long range hyperfine coupling of 0.011 mT.Selective line broadening in the ESR spectrum of the radical cation 4a+* indicates that intramolecular electron transfer between the 1,4-dimethoxybenzene moieties occurs at a moderate rate.The deceleration of the exchange rate compared to the rate expected for a free radical cation is interpreted in terms of ion pairing.