1633-90-5Relevant articles and documents
A novel method for the synthesis of thiols from the corresponding olefins by using thiocarbonates and Ti(IV) halides
Mukaiyama, Teruaki,Saitoh, Terunobu,Jona, Hideki
, p. 638 - 639 (2001)
A convenient method for the preparation of secondary or tertiary thiols from the corresponding olefins was established by using thiocarbonate, titanium(IV) chloride or fluoride and copper(II) oxide. Various thiols were obtained regioselectively in good to excellent yields according to the Markovnikov rule.
Reaction Products and Process of 2-Chloroethyl Ethyl Sulfide in Microemulsion Media
Mei-Ling, Lei,Hai-Ling, Xi,Ming, Shen,Ling, Yuan,Shi-Tong, Han
, p. 387 - 393 (2014/03/21)
The reaction of 2-chloroethyl ethyl sulfide was investigated in several oil-in-water microemulsions. The reaction products were identified by GC/MS, NMR, and LC/MS, and the reaction process was monitored by measuring peak height of reaction products and 2-chloroethyl ethyl sulfide with time by 1H NMR spectroscopy. The result showed that 2-chloroethyl ethyl sulfide degraded to 2-hydroxyethyl ethyl sulfide, cyclic sulfonium ion, open chain sulfonium chloro ion and sulfonium hydroxyl ion, and the reaction proceeded via a cyclic sulfonium ion intermediate. Based on the NMR results, a pseudoternary model was established for the reaction process of 2-chloroethyl ethyl sulfide in microemulsion.