1644494-02-9

Basic information

• Product Name: 1-(m-tolyl)hept-2-yn-1-yl 3,4-dihydro-2H-pyran-6-carboxylate
• Synonyms: 1-(m-tolyl)hept-2-yn-1-yl 3,4-dihydro-2H-pyran-6-carboxylate
• CAS NO: 1644494-02-9
• Molecular Weight: 312.409
• Mol File: 1644494-02-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(m-tolyl)hept-2-yn-1-yl 3,4-dihydro-2H-pyran-6-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(m-tolyl)hept-2-yn-1-yl 3,4-dihydro-2H-pyran-6-carboxylate(1644494-02-9)
• EPA Substance Registry System: 1-(m-tolyl)hept-2-yn-1-yl 3,4-dihydro-2H-pyran-6-carboxylate(1644494-02-9)

Safety Data

• Hazardous Substances Data: 1644494-02-9(Hazardous Substances Data)

Upstream product

• 31518-14-6 3,4-dihydro-2H-pyran-6-carboxylic acid 
• 1138140-73-4 1-(3-methylphenyl)hept-2-ynol 

Relevant articles and documents

Highly diastereoselective synthesis of cyclopentenones via a one-pot gold catalysis, Nazarov cyclization and alkylation cascade

Starting from readily available propargylic carboxylates, three sequential transformations [gold-catalyzed tandem reaction, scandium(III) trifluoromethanesulfonate catalyzed Nazarov cyclization, alkylation reaction] in a one-pot process led to the formation of cyclopentenone derivatives in excellent diastereoselectivities and moderate to good overall yields. Georg Thieme Verlag Stuttgart. New York.