1654-67-7Relevant articles and documents
Production process of cyclohexanecarboxylic acid
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Paragraph 0018; 0023; 0024, (2018/09/08)
The invention discloses a production process of cyclohexanecarboxylic acid and belongs to the field of chemical synthesis. Cyclohexene oxide is used herein as a starting material to react with carbondioxide, Mg powder and TMSCl (trimethylsilyl chloride); Pd/C catalytic hydrogenation is performed in the presence of an acid to obtain the cyclohexanecarboxylic acid. The production process has good safety and good operational simplicity and is suitable for industrial production.
Microbial hydroxylation of 2-cycloalkylbenzoxazoles. Part II. Determination of product structures and enhancement of enantiomeric excess
De Raadt,Griengl,Petsch,Plachota,Schoo,Weber,Braunegg,Kopper,Kreiner,Zeiser
, p. 473 - 490 (2007/10/03)
The determinations of product structures obtained in the microbial hydroxylations of various 2-cycloalkyl-1,3-benzoxazoles using Cunninghamella blakesleeana DSM 1906 and Bacillus megaterium DSM 32 are described. The initially low e.e of 3-(benz-1,3-oxazol
Selective transformation of nitriles into amides and carboxylic acids by an immobilized nitrilase
Klempier,De Raadt,Faber,Grieng
, p. 341 - 344 (2007/10/02)
Using an immobilized nitrilase from Rhodococcus sp. mild and selective hydrolysis of nitriles can be achieved even in the presence of acid or base sensitive groups under neutral conditions. This method is applicable to a broad range of substrates as exemplified by aliphatic, alicyclic, heterocyclic and carbohydrate type nitriles.