16630-66-3 Usage
Description
Methyl (Methylthio)Acetate, also known as Methyl Thioacetate, is a thioether ester compound that is recognized for its significant contribution to the aroma profiles of various fruits, particularly Cucumis melo fruit, and is identified as a new sulfur volatile in strawberries. It possesses a fruity, pungent odor and is reportedly present in a variety of fruits such as cantaloupe, honeydew, watermelon, papaya, pineapple, durian, and kiwifruit.
Uses
1. Used in Chemical Synthesis:
Methyl (Methylthio)Acetate is used as a reagent in chemical synthesis for various applications due to its unique chemical properties.
2. Used in Pharmaceutical Industry:
Methyl (Methylthio)Acetate is used as a reagent for the synthesis of lupeol derivatives, which act as pro-inflammatory cytokine inhibitors. This application is significant in the development of treatments for inflammatory conditions.
3. Used in Flavor and Fragrance Industry:
Given its fruity, pungent odor and presence in various fruits, Methyl (Methylthio)Acetate is used as a component in the flavor and fragrance industry to enhance and create unique scents and tastes in products.
4. Used in Agricultural and Food Industry:
Methyl (Methylthio)Acetate, being a naturally occurring compound in several fruits, may have potential applications in the agricultural and food industry for enhancing the aroma and flavor of fruits and related products.
Check Digit Verification of cas no
The CAS Registry Mumber 16630-66-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,6,3 and 0 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 16630-66:
(7*1)+(6*6)+(5*6)+(4*3)+(3*0)+(2*6)+(1*6)=103
103 % 10 = 3
So 16630-66-3 is a valid CAS Registry Number.
InChI:InChI=1/C4H8O2S/c1-6-4(5)3-7-2/h3H2,1-2H3
16630-66-3Relevant articles and documents
An Electron Spin Resonance Investigation of Free Radicals with Oxigen- and Sulphur-containing Substituents
Beckwith, Athelstan L. J.,Brumby, Steven
, p. 1801 - 1808 (2007/10/02)
Electron spin resonance (e.s.r.) spectra have been recorded during the photolysis of di-t-butyl peroxide in the presence of a number of organic substrates with oxigen- and sulphur-containing functional groups.By hydrogen-atom abstraction, many of the substrates yield more than one species of free radical, the relative concentrations of which have been estimated.These relative concentrations are influenced by the electrophilic character of the t-butoxyl radical, and by the stabilities of the radical generated.Bis(methylthio)methane (2) gives rise to tris(methylthio)methyl radicals (5a), in addition to the two species expected by direct abstraction.Tris(methylthio)methane (5) gives rise to tris(methylthio)methyl radicals (5a) only, which from the measured α(13)C hyperfine splitting constant, appear to be approximately planar.Several of the substrates used give rise to captodative free radicals.The data indicate that alkylcarbonyl groups are more effective than the methoxycarbonyl group in the capto role.The acyclic captodative radicals all exist in two distinct conformations, the likely geometries of which are discussed.Observations on two cyclic radicals suggest that relatively small deviations from a suitable planar conformation can significantly diminish the importance of the captodative effect.
Photochemistry of α-Diazo Thioesters: Migratory Aptitude of Sulfur vs. Oxygen in the Photochemical Wolff Rearrangement
Georgian, V.,Boyer, S. K.,Edwards, B.
, p. 1686 - 1688 (2007/10/02)
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