1669-54-1

Basic information

• Product Name: 1-(4-methylphenyl)-3-phenylprop-2-en-1-ol
• Synonyms: 1-(4-methylphenyl)-3-phenylprop-2-en-1-ol
• CAS NO: 1669-54-1
• Molecular Weight: 224.302
• Mol File: 1669-54-1.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: 1-(4-methylphenyl)-3-phenylprop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methylphenyl)-3-phenylprop-2-en-1-ol(1669-54-1)
• EPA Substance Registry System: 1-(4-methylphenyl)-3-phenylprop-2-en-1-ol(1669-54-1)

Safety Data

• Hazardous Substances Data: 1669-54-1(Hazardous Substances Data)

Upstream product

• 4224-96-8 3-phenyl-1-p-tolylprop-2-en-1-one 
• 4363-35-3 Dihydroxy-styryl-boran 
• 104-87-0 4-methyl-benzaldehyde 
• 14371-10-9 (E)-3-phenylpropenal 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 3883-13-4 2,2,2-trichloroethylbenzene 
• 106-38-7 para-bromotoluene 
• 98-86-2 acetophenone 
• 122-00-9 para-methylacetophenone 
• 100-52-7 benzaldehyde 
• 104-55-2 3-phenyl-propenal 
• 4294-57-9 para-methylphenylmagnesium bromide 

Downstream Products

• 5012-90-8 4-methylphenyl phenethyl ketone 
• 166824-01-7 α-phenyl p-methylcinnamyl alcohol 
• 1352733-26-6 (E)-5-(4-methylstyryl)-1-phenyl-1H-tetrazole 
• 1352733-07-3 (E)-5-styryl-1-(p-tolyl)-1Htetrazole 
• 62056-37-5 1-methyl-4-[(1E)-3-phenylprop-1-en-1-yl]benzene 
• 62056-38-6 (E)-1-phenyl-3-p-tolylpropene 
• 4224-96-8 3-phenyl-1-p-tolylprop-2-en-1-one 
• 1669-50-7 1-phenyl-3-(4-tolyl)propan-1-one 

Relevant articles and documents

Palladium-Catalyzed Synthesis of α-Methyl Ketones from Allylic Alcohols and Methanol

One-pot synthesis of α-methyl ketones starting from 1,3-diaryl propenols or 1-aryl propenols and methanol as a C1 source is demonstrated. This one-pot isomerization-methylation is catalyzed by commercially available Pd(OAc)2 with H2O as the only by-product. Mechanistic studies and deuterium labelling experiments indicate the involvement of isomerization of allyl alcohol followed by methylation through a hydrogen-borrowing pathway in these isomerization-methylation reactions.

Potassium Base-Promoted Diastereoselective Synthesis of 1,3-Diols from Allylic Alcohols and Aldehydes through a Tandem Allylic-Isomerization/Aldol–Tishchenko Reaction

This study reports the first base-promoted aldol–Tishchenko reactions of allylic alcohols with aldehydes initiated by allylic isomerization. The reaction enables the diastereoselective synthesis of a variety of 1,3-diols with three contiguous stereogenic centers. Unlike commonly reported systems, our method allows the use of readily available allylic alcohols as nucleophiles instead of enolizable aldehydes and ketones.

Bi(OTf)3 catalyzed disproportionation reaction of cinnamyl alcohols

Bi(OTf)3 catalyzed disproportionation reaction of cinnamyl alcohols provides chalcones and benzyl styrenes. The use of various metal triflates is investigated herein for facile and efficient redox transformation. A plausible mechanism has been proposed.