1713-63-9Relevant articles and documents
Assembling contiguous quaternary carbon atoms: Regio- and stereoselective rearrangements in cobalt-directed radical reactions of 1,4-enynes
Melikyan, Gagik G.,Hughes, Rhoda,Rivas, Bianca,Duncan, Kellyanne,Sahakyan, Nare
, p. 242 - 253 (2015)
Radical coupling reactions of Co2(CO)6-complexed 1,4-enynes occur in a regio- and stereoselective fashion, providing access to 3E,7E-decadiene-1,9-diynes in excellent yields (84-99%). The formation of contiguous quaternary carbon ato
Yamagami et al.
, p. 2967,2974 (1971)
Organoselenium-catalyzed, hydroxy-controlled regio- and stereoselective amination of terminal alkenes: Efficient synthesis of 3-amino allylic alcohols
Deng, Zhimin,Wei, Jialiang,Liao, Lihao,Huang, Haiyan,Zhao, Xiaodan
supporting information, p. 1834 - 1837 (2015/04/27)
An efficient route to prepare 3-amino allylic alcohols in excellent regio- and stereoselectivity in the presence of bases by orangoselenium catalysis has been developed. In the absence of bases α,β-unsaturated aldehydes were formed in up to 97% yield. Control experiments reveal that the hydroxy group is crucial for the direct amination.
Reduction of nitriles into aldehydes using a TMDS/V(O)(OiPr)3 reducing system
Laval, Stéphane,Dayoub, Wissam,Pehlivan, Leyla,Métay, Estelle,Delbrayelle, Dominique,Mignani, Gérard,Lemaire, Marc
, p. 23 - 26 (2014/01/06)
A simple and convenient method for the chemoselective reduction of nitriles into aldehydes using a 1,1,3,3-tetramethyldisiloxane (TMDS)/ triisopropoxyvanadium(V) oxide reducing system is described. Aromatic as well as aliphatic nitriles are reduced into the corresponding aldehydes in moderate to good yields.
