171975-58-9Relevant articles and documents
Reactions of cis- and cis- with Anhydrous HF and HOTeF5; Compatibility of Phosphine, Alkyl and OTeF5(-) Ligands in Low-valent Transition-metal Complexes
Brewer, Stuart A.,Buggey, Lesley A.,Holloway, John H.,Hope, Eric G.
, p. 2941 - 2944 (1995)
In the reactions of transition metal carbonyl methyls with Hf or HOTeF5 the elimination of methane has been shown to be a strong driving force in the formation of, for example, cis-, cis-, cis- and cis-, which have been characterised by a combination of multinuclear NMR spectroscopic studies.These results also indicate that, with a suitable choice of metals and co-ligands, transition-metal teflate-phosphine and teflate-alkyl complexes can be prepared (teflate = OTeF5(-)).