17241-04-2

Basic information

• Product Name: Benzene, 1,1'-[methylenebis(thio)]bis[4-methyl-
• CAS NO: 17241-04-2
• Molecular Formula: C15H16S2
• Molecular Weight: 260.424
• Mol File: 17241-04-2.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[methylenebis(thio)]bis[4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[methylenebis(thio)]bis[4-methyl-(17241-04-2)
• EPA Substance Registry System: Benzene, 1,1'-[methylenebis(thio)]bis[4-methyl-(17241-04-2)

Safety Data

• Hazardous Substances Data: 17241-04-2(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 106-45-6 para-thiocresol 
• 75-09-2 dichloromethane 
• 103-19-5 di(p-tolyl) disulfide 
• 124-38-9 carbon dioxide 
• 75-52-5 nitromethane 
• 534-17-8 caesium carbonate 
• 50-00-0 formaldehyd 
• 14756-51-5 4-nitrophenyl p-tolyl disulfide 
• 67-64-1 acetone 
• 7647-01-0 hydrogenchloride 
• 64-19-7 acetic acid 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 925-90-6 ethylmagnesium bromide 

Downstream Products

• 52317-51-8 p-Toluyl-p-toluylthiomethylsulfoxid 
• 220997-79-5 bis-(toluene-4-sulfinyl)-methane 
• 91191-99-0 1,1-bis(p-tolylthio)-2-methoxyoctane 
• 5285-74-5 4-tolyl thiocyanate 
• 91191-97-8 1,1-bis(p-tolylthio)-2-<(benzyloxy)methoxy>octane 
• 91191-98-9 1,1-bis(p-tolylthio)-2-(methoxymethoxy)octane 
• 119125-19-8 (2S,3S)-(-)-2,3-bis(phenylmethoxy)-1,1-bis-p-tolylthio-butane 
• 119125-20-1 (2R,3S)-(+)-2,3-bis(phenylmethoxy)-1,1-bis-p-tolylthio-butane 
• 102732-59-2 (4R,5S)-(-)-4-(bis-p-tolylthiomethyl)-2,2,5-trimethyl-1,3-dioxolane 
• 102779-60-2 (4S,5S)-(-)-4-(bis-p-tolylthiomethyl)-2,2,5-trimethyl-1,3-dioxolane 
• 102732-57-0 (2S,3S)-1,1-Bis-p-tolylsulfanyl-butane-2,3-diol 
• 102732-58-1 (2R,3S)-1,1-Bis-p-tolylsulfanyl-butane-2,3-diol 
• 102732-50-3 3-hydroxy-1,1-bis-p-tolylthiobutan-2-one 
• 156808-54-7 p-tolyl 1-p-tolylthioallyl sulfone 

Relevant articles and documents

Reductive α-substitution of sulfoxides with grignard reagents promoted by a magnesium amide

The reactions of sulfoxides bearing α-hydrogen(s) (RSOCHR1R2: R-alkyl or aryl; R1, R2 = H, alkyl, or aryl) with Grignard reagents (R3MgBr: R3 = Et, Ph, or vinyl) in the presence of the diisopropylaminomagnesium reagent, generated in situ by the treatment of diisopropylamine with the appropriate Grignard reagents in diethyl ether, have resulted in the formation of the corresponding sulfides (RSCR1R2R3) in moderate to good isolated yields.

A NOVEL AND CONVENIENT SYNTHESIS OF BISMETHANES

Bismethanes are produced in high yield on treatment of aryl chloromethyl sulphides with neutral alumina.

Sc(OTf)3-Catalyzed Synthesis of Symmetrical Dithioacetals and Bisarylmethanes Using Nitromethane as a Methylene Source

Use of nitromethane as an electrophilic methylene source for the synthesis of symmetrical dithioacetals and bisarylmethanes has been showcased using Sc(OTf)3 as a catalyst. The procedure allows straightforward access to the densely functionalized dithioacetals and bisarylmethanes under mild conditions. Additionally, the method has been applied for the synthesis of antimalarial tetramethyl mellotojaponin C and anticancer dimeric phloroglucinol derivative.

A thioether compound and its synthetic method and application (by machine translation)

The invention belongs to the technical field of sulfur-containing organic synthesis, discloses a thioether compound and its synthetic method and application. The vinyl ether compound is acetone, b of sulfur compounds, inorganic alkali and 18 - crown ether - 6 mixing, heating and stirring, in the inorganic alkali under the action of the catalyst, the reaction under air atmosphere, and then concentrated, purified made, the vinyl ether compound of molecular formula as formula (1) as shown: Wherein R1 And R2 Selected from hydrogen atom, alkyl, alkoxy, nitro, amino, hydroxy, halogen base, acyl, aryl or a heterocyclic group. The method can avoid the toxicity is relatively large of the methylene chloride and halogenated hydrocarbon such as methylene diiodide. The synthesis step is simple, convenient and easy operation, environment friendly and under a comparatively mild condition, have high conversion, the yield of the product can be as high as 96%. The thioether compound can be applied to the production of organic synthetic intermediates in the field. (by machine translation)