17579-99-6Relevant articles and documents
Halo sugar nucleosides. I. Iodination of the primary hydroxyl groups of nucleosides with methyltriphenoxyphosphonium iodide.
Verheyden,Moffatt
, p. 2319 - 2326 (2007/10/07)
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Version: 1.0
Creation Date: Aug 12, 2017
Revision Date: Aug 12, 2017
Product name | METHYLTRIPHENOXYPHOSPHONIUM IODIDE |
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Product number | - |
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Other names | methyl(triphenoxy)phosphanium,iodide |
Identified uses | For industry use only. |
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Uses advised against | no data available |
Emergency phone number | - |
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Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
More Details:17579-99-6 SDS
Conditions | Yield |
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im geschlossenen Rohr; |
tert-butyl (4S,7S,10aS)-7-formyl-5-oxooctahydro-2H-pyrido[2,1-b][1,3]thiazepin-4-ylcarbamate
methyltriphenoxyphosphonium iodide
tert-butyl (4S,7S,10aS)-5-oxo-7-vinyloctahydro-2H-pyrido[2,1-b][1,3]thiazepin-4-ylcarbamate
Conditions | Yield |
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Stage #1: methyltriphenoxyphosphonium iodide With potassium hexamethylsilazane In tetrahydrofuran; toluene at 0 - 20℃; for 0.5h; Inert atmosphere; Stage #2: tert-butyl (4S,7S,10aS)-7-formyl-5-oxooctahydro-2H-pyrido[2,1-b][1,3]thiazepin-4-ylcarbamate In tetrahydrofuran; toluene at -78 - 20℃; for 3h; | 91% |
methyltriphenoxyphosphonium iodide
2-benzyloxycarbonylamino-3-hydroxy-propionic Acid tert-butyl Ester
Conditions | Yield |
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In DMF (N,N-dimethyl-formamide) at 0 - 20℃; for 3.5h; | 85% |
methyltriphenoxyphosphonium iodide
2-amino-phenol
2-methyl-2',3'-dihydro-3H-2λ5-[2,2']spirobi(benzo[1,3,2]oxazaphosphole)
Conditions | Yield |
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With n-butyllithium In tetrahydrofuran; hexane | 75% |
methyltriphenoxyphosphonium iodide
Conditions | Yield |
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In methanol; chloroform; N,N-dimethyl-formamide | 58% |
ethanol
methyltriphenoxyphosphonium iodide
A
diphenyl methylphosphonate
B
ethyl iodide
C
phenol
3-isopropyl-pentane-1,5-diol
methyltriphenoxyphosphonium iodide
1-iodo-3-(2-iodo-ethyl)-4-methyl-pentane
p-methylsulfonylbenzyl alcohol
methyltriphenoxyphosphonium iodide
(4-iodomethyl-phenyl)-methyl sulfone
3β-acetoxy-6α-hydroxymethyl-5α-pregnan-20-one
methyltriphenoxyphosphonium iodide
3β-acetoxy-6α-iodomethyl-5α-pregnan-20-one
Conditions | Yield |
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With methyl iodide |
methyltriphenoxyphosphonium iodide
diphenyl methylphosphonate
Conditions | Yield |
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at 220℃; | |
With sodium hydroxide | |
With sodium hydroxide | |
With butan-1-ol In acetonitrile at -40℃; |
methyltriphenoxyphosphonium iodide
dimethyl amine
methyltriphenoxyphosphonium iodide
diethylamine
diethyl-(methyl-diphenoxy-phosphoranyliden)-ammonium; iodide
methyltriphenoxyphosphonium iodide
(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol
4-iodomethyl-2,2-dimethyl-[1,3]dioxolane
cholesterol
methyltriphenoxyphosphonium iodide
methyl iodide
cholesteryl iodide
6,6-diphenyl-2,3,5,6-tetrahydro-imidazo[2,1-b]thiazol-5-ol
methyltriphenoxyphosphonium iodide
6,6-diphenyl-2,3,5,6-tetrahydro-imidazo[2,1-b]thiazole
Conditions | Yield |
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With sodium cyanoborohydride In N,N,N,N,N,N-hexamethylphosphoric triamide |
2,2'-Anhydrouridine
methyltriphenoxyphosphonium iodide
methylphosphonic acid (3aS)-2t-iodomethyl-6-oxo-(3ar,9ac)-2,3,3a,9a-tetrahydro-6H-furo[2',3':4,5]oxazolo[3,2-a]pyrimidin-3c-yl ester phenyl ester
Conditions | Yield |
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With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 25℃; for 0.25h; |
methyltriphenoxyphosphonium iodide
Conditions | Yield |
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With sodium hydride In tetrahydrofuran 1.) 50-60 deg C, 2.) RT, overnight; |
methyltriphenoxyphosphonium iodide
N,N-dimethyl-formamide dimethyl acetal
A
diphenyl methylphosphonate
B
methyltetraphenoxyphosphorane
C
N,N-dimethyl-formamide
D
methyl iodide
Conditions | Yield |
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In dichloromethane for 2h; Ambient temperature; |
methyltriphenoxyphosphonium iodide
but-2t(?)-en-1-ol
(E)-crotyl iodide
Conditions | Yield |
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at 0℃; |
methyltriphenoxyphosphonium iodide
toluene
sodium
methylphosphine
Conditions | Yield |
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anschliessendes Behandeln mit wss. Methanol; |
methyltriphenoxyphosphonium iodide
A
diphenyl methylphosphonate
B
hydrogen iodide
C
phenol
2,6-dimethylpyridine
hexanes-EtOAc
methyltriphenoxyphosphonium iodide
5'-O-(tert-butydiphenylsilyl)-3'-deoxy-3'-C-(hydroxymethyl)-2'-O-(2-methoxyethyl)-5-methyluridine
5'-O-(tert-butydiphenylsilyl)-3'-deoxy-3'-C-(iodomethyl)-2'-O-(2-methoxyethyl)-5-methyluridine
Conditions | Yield |
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In ethyl acetate; N,N-dimethyl-formamide | |
In ethyl acetate; N,N-dimethyl-formamide |
methyltriphenoxyphosphonium iodide
methyl 4-(4-hydroxy-1-butyl)phenylacetate
methyl 4-(4-iodobutyl)phenylacetate
Conditions | Yield |
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In hexane; ethyl acetate; acetonitrile | 4.12 g (71%) |
morpholine
4-N-[4-(2-hydroxyethyl)phenyl]amino-5-phenyl-7-(2,3-O-(methylethylidene)-β-D-erythrofuranosyl)pyrrolo[2,3-d]pyrimidine
methyltriphenoxyphosphonium iodide
4-N-[4-(2-(4-morpholino)ethyl)phenyl]amino-5-phenyl-7-(2,3-O-(methylethylidene)-β-D-erythrofuranosyl)pyrrolo[2,3-d]pyrimidine
Conditions | Yield |
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With sodium thiosulfate In 1,4-dioxane; dichloromethane |
2-(β-hydroxy-β-phenylethyl)morpholine
ethereal oxalic acid
methyltriphenoxyphosphonium iodide
2-(β-phenyl-trans-vinyl)morpholine hydrogen oxalate
Conditions | Yield |
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In N,N,N,N,N,N-hexamethylphosphoric triamide |
methyltriphenoxyphosphonium iodide
silver trifluoromethanesulfonate
Methyl-triphenoxyphosphonium-trifluormethansulfonat
Conditions | Yield |
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byproducts: AgI; | |
byproducts: AgI; |
1-(2-methoxy-5-(trifluoromethyl)phenyl)ethan-1-one
methyltriphenoxyphosphonium iodide
Conditions | Yield |
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Stage #1: methyltriphenoxyphosphonium iodide With potassium tert-butylate In tetrahydrofuran at 0℃; for 2h; Stage #2: 1-(2-methoxy-5-(trifluoromethyl)phenyl)ethan-1-one In tetrahydrofuran at 20℃; for 1h; |
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