175923-07-6

Basic information

• Product Name: LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]
• Synonyms: LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE];LANTHANUM TRIS(HEXAMETHYLDISILAZIDE);TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDO]LANTHANUM;TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]LANTHANUM (III);TrisN,N-bis(trimethylsilyl)amideülanthanum(III), 97%;Lanthanum (III) tris[N,N-bis(trimethylsiyl)amide] 99,9%;Tris[N,N-bis(trimethylsilyl)amide]lanthanum(Ⅲ);Lanthanum (III) tris[N,N-bis(trimethylsiyl)amide]
• CAS NO: 175923-07-6
• Molecular Formula: C18H54LaN3Si6
• Molecular Weight: 620.06
• Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Lanthanum;LanthanumVapor Deposition Precursors;Precursors by Metal;organometallic complex
• Mol File: 175923-07-6.mol
• Article Data: 0

Chemical Properties

• Melting Point: 149-153 °C(lit.)
• Boiling Point: 126 °C at 760 mmHg
• Flash Point: 36 °F
• Appearance: white/Powder
• Vapor Pressure: 11.9mmHg at 25°C
• Sensitive: Air & Moisture Sensitive
• CAS DataBase Reference: LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE](CAS DataBase Reference)
• NIST Chemistry Reference: LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE](175923-07-6)
• EPA Substance Registry System: LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE](175923-07-6)

Safety Data

• Hazard Codes: F,C
• Statements: 11-14/15-34
• Safety Statements: 16-26-36/37/39-43-45-7/8
• RIDADR: UN 3396 4.3/PG 2
• WGK Germany: 3
• HazardClass: 4.1
• PackingGroup: II
• Hazardous Substances Data: 175923-07-6(Hazardous Substances Data)

Usage

Reactions

Catalyst precursor for enantioselective intramolecular hydroamination of aminoalkenes and aminodienes.? Catalyzes a mild and highly selective addition of terminal alkynes to nitriles to form conjugated ynones. Catalytic amidation of aldehydes with amines.

InChI:InChI=1/3C6H18NSi2.La/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3