1767-71-1Relevant articles and documents
I2O5/DBU mediated direct α-phosphoryloxylation of ketones with H-phosphonates leading to α-hydroxyketone phosphates
Liu, Chunli,Wei, Wei,Yang, Daoshan,Zheng, Yuanyuan,Bi, Yanshuai,Chen, Min,Wang, Hua
, p. 6901 - 6906 (2015)
A simple and convenient procedure has been developed for the construction of α-hydroxyketone phosphates via I2O5/DBU mediated direct α-phosphoryloxylation of ketones with H-phosphonates. This new reaction proceeds through three steps involving α-iodination of ketones, oxidation of H-phosphonates, and nucleophilic substitution of α-iodo ketones to access a series of α-hydroxyketone phosphates of biological importance.