17774-38-8 Usage
Description
(Ethylselanyl)benzene, also known as ethylphenylselenium, is an organoselenium compound characterized by the molecular formula C10H14Se. It features a benzene ring with an ethyl group and a selenium atom attached. (ethylselanyl)benzene is predominantly utilized in research and academic studies, serving as a precursor to a variety of organoselenium compounds. Organoselenium compounds are of interest due to their potential applications in the medical field and their antioxidant and anti-inflammatory properties. However, (ethylselanyl)benzene has restricted commercial use because of its toxicity and potential health risks, necessitating careful handling in laboratory environments.
Uses
Used in Research and Academic Studies:
(Ethylselanyl)benzene is used as a precursor in the synthesis of various organoselenium compounds for research and academic studies. Its role in creating these compounds is crucial for exploring their potential applications and properties.
Used in Pharmaceutical Development:
(Ethylselanyl)benzene is used as a starting material for the development of organoselenium compounds with potential pharmaceutical applications. These compounds are investigated for their possible use in medicine, particularly in relation to their antioxidant and anti-inflammatory characteristics.
Used in Antioxidant and Anti-Inflammatory Studies:
(Ethylselanyl)benzene is used as a research compound to study the antioxidant and anti-inflammatory properties of organoselenium compounds. Understanding these properties can lead to the development of new treatments for various diseases and conditions.
Used in Chemical Synthesis:
(Ethylselanyl)benzene is used as an intermediate in the chemical synthesis of other organoselenium compounds, which may have a range of applications in different industries, including pharmaceuticals, agriculture, and materials science.
Check Digit Verification of cas no
The CAS Registry Mumber 17774-38-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,7,7 and 4 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 17774-38:
(7*1)+(6*7)+(5*7)+(4*7)+(3*4)+(2*3)+(1*8)=138
138 % 10 = 8
So 17774-38-8 is a valid CAS Registry Number.
17774-38-8Relevant articles and documents
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Detty
, p. 5087 (1978)
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Foster
, p. 822,826 (1933)
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Production of Alkyl Aryl Sulfides from Aromatic Disulfides and Alkyl Carboxylates via a Disilathiane–Disulfide Interchange Reaction
Nakajima, Takumi,Takano, Ken,Maeda, Hiromu,Ogiwara, Yohei,Sakai, Norio
supporting information, p. 4103 - 4107 (2021/11/10)
The results of this study show that disilathiane is an effective mediator in the synthesis of alkyl aryl sulfides with disulfides and alkyl carboxylates. Mechanistic studies suggest that disilathiane promotes cleavage of the sulfur–sulfur bond of disulfides to generate thiosilane as a key intermediate. Diselenides were also applicable to this transformation to produce the corresponding selenides.
Copper-Catalyzed Three-Component Coupling Reaction of Aryl Iodides, a Disilathiane, and Alkyl Benzoates Leading to a One-Pot Synthesis of Alkyl Aryl Sulfides
Sakai, Norio,Maeda, Hiromu,Ogiwara, Yohei
, p. 2323 - 2330 (2019/05/24)
A copper-catalyzed three-component coupling reaction of aryl iodides, hexamethyldisilathiane and alkyl benzoates leading to alkyl aryl sulfides has been demonstrated. A disilathiane acted as both a sulfur source and a promoter of the sulfidation, and the alkyl moiety of the alkyl benzoate was effectively introduced on one side of the sulfide. Moreover, we found that the protocol can be expanded to the preparation of ethyl phenyl selenide with diphenyl diselenide.