17961-78-3

Basic information

• Product Name: Silane, trimethyl(1-phenylethyl)-
• Synonyms: 1-phenyl-1-trimethylsilylethane;1-Phenyl-1-trimethylsilylethan
• CAS NO: 17961-78-3
• Molecular Formula: C11H18Si
• Molecular Weight: 178.349
• Mol File: 17961-78-3.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(1-phenylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(1-phenylethyl)-(17961-78-3)
• EPA Substance Registry System: Silane, trimethyl(1-phenylethyl)-(17961-78-3)

Safety Data

• Hazardous Substances Data: 17961-78-3(Hazardous Substances Data)

Upstream product

• 98-85-1 1-Phenylethanol 
• 75-77-4 chloro-trimethyl-silane 
• 14296-15-2 (RS)-α-methylbenzenemethyl 2,2-dimethylpropanoate 
• 4013-34-7 3-phenyl-2-oxabutane 
• 38053-74-6 (1-phenylethyl)trichlorosilane 
• 676-58-4 methylmagnesium chloride 
• 100-42-5 styrene 
• 993-07-7 trimethylsilan 
• 585-71-7 (1-bromoethyl)benzne 
• 7100-97-2 1-fluoro-1-phenylethane 
• 252031-74-6 tert-butyl 1-phenylethyl carbonate 
• 197958-51-3 2,2,N-Trimethyl-N-(1-phenyl-ethyl)-propionamide 
• 14856-75-8 1-phenyl-1-trimethylsilyloxyethane 
• 672-65-1 (1-chloroethyl)benzene 

Downstream Products

• 71435-96-6 <(1.4-Cyclohexadien-1-yl)ethyl>trimethylsilan 
• 136289-31-1 1,4-dicyano-1-(α-methylbenzyl)naphthalene 
• 136289-31-1 1,4-dicyano-1-(α-methylbenzyl)naphthalene 
• 139097-57-7 4-cyano-1-(α-methylbenzyl)-naphthalene 
• 89103-72-0 (1S,2S)-1,2-diphenylpropan-1-ol 
• 7693-84-7 (1S,2R)-1,2-diphenylpropan-1-ol 
• 1502-73-4 erythro-2-Phenyl-4,4-dimethyl-3-pentanol 
• 738617-33-9 (3S,4S)-2,2-dimethyl-4-phenyl-3-pentanol 
• 81290-09-7 2-trimethylsilyl-1,2-diphenylpropane 
• 19263-14-0 3-Phenyl-1,2-butanedicarboxylic acid 
• 3279-79-6 8-Isopropyl-coffein 

Relevant articles and documents

Regioselective Silylations of Propargyl and Allyl Pivalates through Ca-Promoted Reductive C(sp3)-O Bond Cleavage

A practical protocol for the regioselective preparation of 3-phenylpropargylsilanes and 3-phenylallylsilanes in yields of 36-77 and 48-86%, respectively, from readily accessible 3-phenylpropargyl and 1-phenylallyl pivalates was developed through reductive C(sp3)-O bond cleavage. This method represents the first example of the direct application of vastly abundant calcium granules to a reductive coupling reaction. A broad range of propargylsilanes and allylsilanes are simply prepared using easy-to-handle pivalates and chlorotrimethylsilane under mild catalyst-free and additive-free conditions.

Fluoroalkylselenolation of Alkyl Silanes/Trifluoroborates under Metal-Free Visible-Light Photoredox Catalysis

Herein a metal-free fluoroalkylselenolation of alkylsilanes as well as potassium alkyltrifluoroborates under visible light photocatalysis is disclosed. The developed methodologies are performed under mild conditions, room temperature in the presence of an organic photocatalyst and blue LED irradiation. Mechanistic investigations including luminescence and EPR spectroscopy allow us to shed light on both mechanisms.

METALLATED BENZYLSILANES AND THEIR USE AS POLYMERIZATION INITIATORS

The invention relates to novel compounds useful as polymerization initiators or precursors for polymerization initiators. The invention further relates to a method of making the polymerization initiators and resulting polymers. The invention also relates