1799-84-4Relevant articles and documents
Method for Producing Fluorine-Containing Alkyl (Meth)Acrylate
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Page/Page column 5, (2009/02/11)
The present invention discloses a method for producing a fluorine-containing alkyl (meth)acrylate represented by the following general formula (2): [in-line-formulae]Rf—(CH2)k-[-A-(CH2)l—]m—OCOCR═CH2??(2)[/in-line-formulae] (wherein R is a hydrogen atom or a methyl group), characterized by reacting a fluorine-containing alcohol represented by the following general formula (1): [in-line-formulae]Rf—(CH2)k-[-A-(CH2)l—]m—OH??(1)[/in-line-formulae] (wherein Rf is a perfluoroalkyl group having 1 to 21 carbon atoms; A is S, SO or SO2; k is 0, 1 or 2; 1 is k, 2 or 3; m is 0 or 1; however, a case of k=0 and m=0 is excluded), (meth)acrylic acid, anda sulfonic acid halide in the presence of a base containing at least one kind of tertiary amine.