18027-28-6

Basic information

• Product Name: trimethyl(2-phenylpropyl)silane
• Synonyms: trimethyl(2-phenylpropyl)silane
• CAS NO: 18027-28-6
• Molecular Weight: 192.376
• Mol File: 18027-28-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: trimethyl(2-phenylpropyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl(2-phenylpropyl)silane(18027-28-6)
• EPA Substance Registry System: trimethyl(2-phenylpropyl)silane(18027-28-6)

Safety Data

• Hazardous Substances Data: 18027-28-6(Hazardous Substances Data)

Upstream product

• 13617-28-2 2-phenyl-2-methylethyl (methyl)-dichlorosilane 
• 75-16-1 methylmagnesium bromide 
• 98-83-9 isopropenylbenzene 
• 54380-53-9 cyclohexa-2,5-dien-1-yl(trimethyl)silane 
• 68669-68-1 (3E)-4-phenyl-1-trimethylsilyl-3-penten-1-yne 
• 13617-25-9 3-phenyl-1,1,1-trichloro-1-silabutane 
• 762-72-1 allyl-trimethyl-silane 

Relevant articles and documents

Iridium-catalysed asymmetric hydrogenation of vinylsilanes as a route to optically active silanes

The first use of vinylsilanes as substrates in the asymmetric iridium-catalysed hydrogenation is reported, providing products with enantioselectivities of up to 98%.

Use of cyclohexa-2,5-dien-1-yl-silanes as precursors for gaseous hydrosilanes

The invention relates to the use of cyclohexa-2,5-dien-1-yl-silanes of general formula I for generation of hydrosilanes in solution using a strong Lewis acid. This way, e.g., alkenes can be hydrosilylated in good yields using the cyclohexa-2,5-dien-1-yl-silanes of general formula I as transfer hydrosilylating agents in the presence of a strong Lewis acid as catalyst with concomitant formation of an arene solvent.

3-silylated cyclohexa-1,4-dienes as precursors for gaseous hydrosilanes: The B(C6F5)3-catalyzed transfer hydrosilylation of alkenes

Set Me3SiH free! The strong Lewis acid B(C6F 5)3 catalyzes the release of hydrosilanes from 3-silylated cyclohexa-1,4-dienes with concomitant formation of benzene. Subsequent B(C 6F5)3