18084-64-5 Usage
Description
1,4,7,10-Tetrabenzyl-1,4,7,10-tetraazacyclododecane, also known as tetrabenzylated cyclam, is a synthetic compound with a cyclic structure containing four nitrogen atoms. It is a derivative of cyclam, a macrocyclic polyamine, where each nitrogen atom is connected to a benzyl group. 1,4,7,10-Tetrabenzyl-1,4,7,10-tetraazacyclododecane exhibits unique properties and has potential applications in various fields.
Uses
Used in Fluoride Receptors:
1,4,7,10-Tetrabenzyl-1,4,7,10-tetraazacyclododecane is used as a fluoride receptor in its solid state. 1,4,7,10-Tetrabenzyl-1,4,7,10-tetraazacyclododecane has a high affinity for fluoride ions, making it a promising candidate for the selective capture and removal of fluoride from various sources, such as industrial wastewater or contaminated groundwater.
Used in Chemical Sensors:
Due to its ability to selectively bind fluoride ions, 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane can be employed as a chemical sensor for detecting and monitoring fluoride concentrations in different environments. This application can be particularly useful in environmental monitoring and public health.
Used in Catalysts:
The unique structure and properties of 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane make it a potential candidate for use as a catalyst in various chemical reactions. Its ability to form stable complexes with metal ions and its tunable electronic properties can be exploited to enhance the efficiency and selectivity of catalytic processes.
Used in Supramolecular Chemistry:
1,4,7,10-Tetrabenzyl-1,4,7,10-tetraazacyclododecane can be utilized in supramolecular chemistry for the construction of complex molecular architectures and assemblies. Its ability to form host-guest complexes with various guest molecules can be employed to create novel materials with unique properties and functions.
Used in Pharmaceutical Industry:
The tetrabenzylated cyclam may also have potential applications in the pharmaceutical industry, as it can be used as a building block for the development of new drugs or drug delivery systems. Its ability to form stable complexes with metal ions and its tunable properties can be exploited to design drugs with improved pharmacokinetics and therapeutic efficacy.
Flammability and Explosibility
Nonflammable
Check Digit Verification of cas no
The CAS Registry Mumber 18084-64-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,0,8 and 4 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 18084-64:
(7*1)+(6*8)+(5*0)+(4*8)+(3*4)+(2*6)+(1*4)=115
115 % 10 = 5
So 18084-64-5 is a valid CAS Registry Number.
InChI:InChI=1/C36H44N4/c1-5-13-33(14-6-1)29-37-21-23-38(30-34-15-7-2-8-16-34)25-27-40(32-36-19-11-4-12-20-36)28-26-39(24-22-37)31-35-17-9-3-10-18-35/h1-20H,21-32H2
18084-64-5Relevant articles and documents
THE ANODIC TETRAMERIZATION OF THE N-BENZYLAZIRIDINE : A CHAIN PROCESS
Kossai, Ridha,Simonet, Jacques,Dauphin, Gerard
, p. 3575 - 3578 (1980)
Benzylaziridine is oxidized anodically in organic solvents.The tetramer (tetra-aza-cyclododecane) is obtained in good yield and the electrical consumption is very low.Authors propose a chain process mechanism in comparison with the chemical method.
Tetrabenzylcyclen as a receptor for fluoride
Gelmboldt, Vladimir O.,Ganin, Eduard V.,Basok, Stepan S.,Kulygina, Ekaterina Yu.,Botoshansky, Mark M.,Kravtsov, Victor Ch.,Fonari, Marina S.
, p. 3682 - 3685 (2011)
A tetraazacyclic ligand, tetrabenzylcyclen (L), was synthesized using an improved method with a higher yield by treatment of cyclen with benzylchloride in the presence of potassium carbonate. The reaction of L with an aqueous solution of fluorosilicic aci
A direct method for the N-tetraalkylation of azamacrocycles
Counsell, Andrew J.,Jones, Angus T.,Todd, Matthew H.,Rutledge, Peter J.
, p. 2457 - 2461 (2016/12/09)
An efficient protocol for the direct synthesis of N-tetraalkylated derivatives of the azamacrocycles cyclam and cyclen has been developed, using a partially miscible aqueous-organic solvent system with propargyl bromide, benzyl bromide, and related halide
