18099-26-8

Basic information

• Product Name: 2,4,6-triisopropyl-benzenesulfinic acid
• Synonyms: 2,4,6-triisopropyl-benzenesulfinic acid
• CAS NO: 18099-26-8
• Molecular Weight: 268.42
• Mol File: 18099-26-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4,6-triisopropyl-benzenesulfinic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-triisopropyl-benzenesulfinic acid(18099-26-8)
• EPA Substance Registry System: 2,4,6-triisopropyl-benzenesulfinic acid(18099-26-8)

Safety Data

• Hazardous Substances Data: 18099-26-8(Hazardous Substances Data)

Upstream product

• 82965-03-5 2,4,6-triisopropyl-benzenesulfonic acid n-hexylester 

Downstream Products

• 117659-09-3 2,4,6-triisopropylbenzenesulfinyl chloride 
• 253316-04-0 (RS)-N-(carbomethoxy)-2,4,6-triisopropylbenzenesulfonimidoyl chloride 
• 253316-10-8 (-)-(R)-N-[carbo-(1R)-menthoxy]-2,4,6-triisopropylbenzenesulfonimidoyl chloride 
• 20875-34-7 1,2-bis(2,4,6-triisopropylphenyl)disulfane 
• 989-39-9 S-(2,4,6-triisopropylphenyl) 2,4,6-triisopropylbenzenesulfinothioate 

Relevant articles and documents

STUDIEN ZUM VORGANG DER WASSERSTOFFUEBERTRAGUNG 64. ELECTROREDUCTIVE SPALTUNG VON ARYLSULFONSAEUREDERIVATEN UND ARYLSULFONEN MIT ALKALI-AMALGAMEN

Arylsulfonylchlorides, n-hexylarylsulfonates and di-aryl sulfones (ArSO2Y; Y=Cl, OC6H13, Ar') were cleaved under standard conditions by alkali metal amalgams (M/Hg; M=Li, Na, K) to the corresponding sulfinate salts (ArSO2M) and MY, as shown in Eq. 1.The substrates ArSO2Y in toluene were not cleaved by Li/Hg alone; first on addition of an equimolar amount of i-propanol could conversions of almost 100percent be achieved. (Tables I,II,III).A series of six n-hexylarylsulfonates were studied under standard conditions, to establish the influence of the reaction medium and the amalgam on the course of reaction, (Table II).The sterically hindered arylsulfonates ArSO2OC6H13, (Ar= mesityl, 2,4,6-tri-isopropyl) were "anomalous", i.e. underwent fission at the ring/sulfur bond , as shown by Eq. 2.Table III describes the reductive fission of mesityl-phenylsulfone and dimesitylsulfone.