182216-98-4

Basic information

• Product Name: (3R,4R,5S,1'R)-3-[N-(benzyloxycarbonyl)amino]-5-[1-(isopropyldimethylsilanyloxy)ethyl]-4-methoxytetrahydrofuran-2-one
• Synonyms: (3R,4R,5S,1'R)-3-[N-(benzyloxycarbonyl)amino]-5-[1-(isopropyldimethylsilanyloxy)ethyl]-4-methoxytetrahydrofuran-2-one
• CAS NO: 182216-98-4
• Molecular Weight: 409.555
• Mol File: 182216-98-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3R,4R,5S,1'R)-3-[N-(benzyloxycarbonyl)amino]-5-[1-(isopropyldimethylsilanyloxy)ethyl]-4-methoxytetrahydrofuran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5S,1'R)-3-[N-(benzyloxycarbonyl)amino]-5-[1-(isopropyldimethylsilanyloxy)ethyl]-4-methoxytetrahydrofuran-2-one(182216-98-4)
• EPA Substance Registry System: (3R,4R,5S,1'R)-3-[N-(benzyloxycarbonyl)amino]-5-[1-(isopropyldimethylsilanyloxy)ethyl]-4-methoxytetrahydrofuran-2-one(182216-98-4)

Safety Data

• Hazardous Substances Data: 182216-98-4(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 182216-93-9 (R)-((2R,5S)-3,6-Diethoxy-5-isopropyl-2,5-dihydro-pyrazin-2-yl)-((4R,5R)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-methanol 
• 182216-96-2 ethyl (2R,3R,4S,5R)-2-[N-(benzyloxycarbonyl)amino]-4,5-isopropylidenedioxy-3-methoxyhexanoate 
• 182216-94-0 (3R,6S,1'R,2'S,3'R)-2,5-diethoxy-3,6-dihydro-3-(2,3-isopropylidenedioxy-1-methoxybutyl)-6-isopropylpyrazine 
• 182216-95-1 ethyl (2R,3R,4S,5R)-2-amino-4,5-isopropylidenedioxy-3-methoxyhexanoate 
• 3634-56-8 isopropyldimethylsilyl chloride 
• 182216-97-3 (3R,4R,5S,1'R)-3-[N-(benzyloxycarbonyl)amino]-5-(1-hydroxyethyl)-4-methoxytetrahydrofuran-2-one 

Relevant articles and documents

Amino acid based diastereoselective synthesis of elsaminose

Optically pure (+)-elsaminose (2), the amino sugar contained in the antitumor antibiotic elasmicin A, has been synthesized in eight steps (26% overall yield) from known building blocks derived from glycine, L-valine, and L-threonine. Direct and selective construction of the key intermediate 6, with the complete backbone and the proper stereochemical configuration, is accomplished by a syn-aldol type reaction between lithiated Schollkopf's bislactime ether 5 and a 1,3-dioxolane-4-carboxaldehyde (-)-3.