18385-87-0Relevant articles and documents
Diastereoselective Synthesis of Cyclic sp 3 -Enriched cis -β-Alkoxysulfonyl Chlorides
Sokolov, Andriy,Golovach, Sergey,Kozlinsky, Ihor,Dolia, Krystyna,Tolmachev, Andrey A.,Kuchkovska, Yuliya,Grygorenko, Oleksandr O.
supporting information, p. 848 - 858 (2019/02/10)
A three-step synthesis of β-alkoxy-substituted alicyclic sulfonyl chlorides from cyclic alkenes and alcohols is reported. The scope of the method was studied for a range of the substrates with various steric and electronic properties. The title compounds were obtained on a hundred-gram scale in up to 52% overall yield scale as single cis -diastereomers.
Copper-Catalyzed Asymmetric Hydroboration of 2 H-Chromenes Using a Chiral Diphosphine Ligand
Li, Xiufen,Wang, Chaoqiong,Song, Jianqiao,Yang, Zhihong,Zi, Guofu,Hou, Guohua
, p. 8638 - 8645 (2019/08/30)
A highly regioselective asymmetric hydroboration of 2H-chromenes catalyzed by the complex of CuCl and diphosphine ligand (S,R)-DuanPhos has been realized under mild conditions to produce 3-boryl chromans, achieving good yields and excellent enantioselectivities up to 96% ee. This work provides an efficient approach to the synthesis of chiral 3-boryl chromans and derivatives.
2H-chromenes generated by an iron(III) complex-catalyzed allylic cyclization
Calmus,Corbu,Cossy
supporting information, p. 1381 - 1386 (2015/05/19)
A straightforward method based on an iron(III) complex-catalyzed cyclization of 2-(1-hydroxyallyl)phenols is reported to access a large variety of 2H-chromenes. This method was applied to the total synthesis of a natural product, tephrowatsin B.