18506-88-2

Basic information

• Product Name: N-(ethoxycarbonyl)-p-nitrobenzenesulfinimidoyl chloride
• Synonyms: N-(ethoxycarbonyl)-p-nitrobenzenesulfinimidoyl chloride
• CAS NO: 18506-88-2
• Molecular Weight: 276.7
• Mol File: 18506-88-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(ethoxycarbonyl)-p-nitrobenzenesulfinimidoyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: N-(ethoxycarbonyl)-p-nitrobenzenesulfinimidoyl chloride(18506-88-2)
• EPA Substance Registry System: N-(ethoxycarbonyl)-p-nitrobenzenesulfinimidoyl chloride(18506-88-2)

Safety Data

• Hazardous Substances Data: 18506-88-2(Hazardous Substances Data)

Upstream product

• 101414-53-3 diethyl N-(p-nitrophenylthio)carbonimidate 
• 937-32-6 4-nitrobenzenesulfenyl chloride 
• 101414-49-7 N-(diethoxymethylene)amino(p-nitrophenyl)dichlorosulfurane 
• 13698-16-3 ethyl N,N-dichlorocarbamate 

Downstream Products

• 101414-59-9 N¹-methyl-N²-(ethoxycarbonyl)-p-nitrobenzenesulfinamidine 
• 101466-27-7 N¹,N¹-dimethyl-N²-(ethoxycarbonyl)-p-nitrobenzenesulfinamidine 
• 18513-05-8 C₉H₁₀N₂O₅S 
• 111680-13-8 C₁₈H₁₈N₄O₈S₂ 
• 101414-58-8 N-(ethoxycarbonyl)-p-nitrobenzenesulfinimidomorpholide 
• 22819-41-6 N-(4-Nitro-benzolsulfenyl)-urethan 

Relevant articles and documents

REACTION OF ARENESULFENYL CHLORIDES WITH N-CHLOROCARBONIMIDIC AND N-CHLOROBENZENECARBOXIMIDIC ESTERS. N-(ETHOXYCARBONYL)- AND N-BENZOYLARENESULFINIMIDOYL CHLORIDES

In the reaction of arenesulfonyl chlorides with diethyl N-chlorocarbonimidate or N-chlorobenzenecarboximidic esters at 20 deg C 1:1 adducts are formed, and they probably have the structure of tetracoordinated compounds of sulfur.The latter are also formed during the chlorination of N-(arylthio)carbonimidic or N-(arylthio)benzenecarboximidic esters.The obtained compounds are dechlorinated by the action of bases with the formation of N-(arylthio)carbonimidic or N-(arylthio)benzenecarboximidic esters.During acidolysis they split into arenesulfenyl chlorides and the salts of the corresponding carbonimidic and benzenecarboximidic esters.During thermolysis they eliminate alkyl chlorides and are converted into N-(ethoxycarbonyl)- or N-benzoylarenesulfinimidoyl chlorides.