1858-99-7Relevant articles and documents
The syntheses, structures and spectroelectrochemical properties of 6-oxo-verdazyl derivatives bearing surface anchoring groups
Cox, Nicholas,Judd, Martyna,Korb, Marcus,Kumar, Varshini J.,Low, Paul J.,Moggach, Stephen A.,Rousset, Elodie,Wu, Jian-Zhong
, p. 1896 - 1915 (2022/02/17)
A series of 6-oxo-verdazyl radicals functionalised at the 1-and 5-positions by tolyl, thioanisole and iodophenyl groups were synthesised using conventional strategies. Facile Sonogashira cross-coupling reactions of terminal alkynes with the diiodo derivat
Mn(III)-mediated phosphinoylation of aldehyde hydrazones: Direct “one-pot” synthesis of α-iminophosphine oxides from aldehydes
Bian, Xue-Wei,Zhang, Ling,Shoberu, Adedamola,Zou, Jian-Ping
supporting information, (2021/04/02)
A “one-pot” strategy for the straightforward Mn(III)-mediated phosphinoylation of aldehyde hydrazones with diphenylphosphine oxide to furnish α-iminophosphine oxides is described. This mild and practical method allows the direct use of aldehydes as substrates in one pot to generate the hydrazones, which are then engaged “in situ” by the phosphorus reagent in the presence of Mn(OAc)3 oxidant. Thus, the requisite isolation of the hydrazones is not needed in this operation. Conducted mechanistic experiments implicate a pathway involving phosphorus-centered radicals.
A strongly Lewis-acidic and fluorescent borenium cation supported by a tridentate formazanate ligand
Katzman, Benjamin D.,Maar, Ryan R.,Cappello, Daniela,Sattler, Madeleine O.,Boyle, Paul D.,Staroverov, Viktor N.,Gilroy, Joe B.
supporting information, p. 9530 - 9533 (2021/09/28)
Lewis acids are highly sought after for their applications in sensing, small-molecule activation, and catalysis. When combined with π-conjugated molecular frameworks, Lewis acids with unique optoelectronic properties can be realized. Here, we use a triden
