18758-54-8Relevant articles and documents
Tris(pentafluorophenyl)boron-catalyzed hydrosilation of aromatic aldehydes, ketones, and esters
Parks, Daniel J.,Piers, Warren E.
, p. 9440 - 9441 (1996)
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Exploring Multistep Continuous-Flow Hydrosilylation Reactions Catalyzed by Tris(pentafluorophenyl)borane
Wilkins, Lewis C.,Howard, Joseph L.,Burger, Stefan,Frentzel-Beyme, Louis,Browne, Duncan L.,Melen, Rebecca L.
supporting information, p. 2580 - 2584 (2017/08/16)
Exploring the combination of continuous-flow processes with the boron Lewis acid catalyzed hydrosilylation of aldehydes and ketones has delivered a robust and generally applicable reaction protocol. Notably this approach permits ready access to high temperatures and pressures and thus allows improved reactivity of substrates that were previously recalcitrant under the traditional approach. Efforts to quench the output from the flow reactor with water showed surprising tolerance leading to the application of continuous-flow systems in multistep imine formation/hydrosilylation processes to generate the corresponding secondary amines from their aldehyde and aniline precursors. (Figure presented.).
Hydrosilylation of various multiple bonds by a simple combined catalyst of a tungstate monomer and rhodium acetate
Itagaki, Shintaro,Sunaba, Hanako,Kamata, Keigo,Yamaguchi, Kazuya,Mizuno, Noritaka
, p. 980 - 982 (2013/09/24)
In the presence of a simple combined catalyst of a tungstate monomer (TBA2WO4, TBA: tetra-n-butylammonium) and rhodium acetate (Rh2(OAc)4), hydrosilylation of various types of substances including ketone, aldehyde, carbon dioxide, alkene, nitrile, and fur
