1883-96-1Relevant articles and documents
Study of N-benzylidene derivatives synthesized as corrosion inhibitors for copper in HCl solution
Shabani-Nooshabadi, Mehdi,Behpour, Mohsen,Razavi, Faezeh Sadat,Hamadanian, Masood,Nejadshafiee, Vajihe
, p. 23357 - 23366 (2015)
Corrosion inhibition of the two N-benzylidene derivative compounds, namely N-benzylidene pyridin-2 amine (NBPA) and N-(4-choloromethylbenzylidene) pyridin-2 amine (NCMBPA) as corrosion inhibitors for copper in hydrochloric acid 6.0 M have been studied by
Functional POM-catalyst for selective oxidative dehydrogenative couplings under aerobic conditions
Samaraj, Elavarasan,Balaraman, Ekambaram,Manickam, Sasidharan
, (2021/02/05)
Development of selective and efficient reusable catalytic systems for sustainable chemical production under benign conditions is attractive and received much attention. Herein, we report a rod-shaped octadecyl trimethylammonium functionalized Keggin-type polyoxometalate [PMO12O40] hybrids (OTA-POM) as an efficient heterogeneous catalyst for selective oxidative dehydrogenative couplings under aerobic conditions without any additive or external base. The catalyst recovery and subsequent five successive recyclability studies of hybrid POM confirms the heterogeneous nature of present catalytic system.
Rh(III)-Catalyzed imidoyl C-H carbamylation and cyclization to bicyclic [1,3,5]triazinones
Confair, Danielle N.,Greenwood, Nathaniel S.,Mercado, Brandon Q.,Ellman, Jonathan A.
supporting information, p. 8993 - 8997 (2020/11/30)
A Rh(III)-catalyzed synthesis of bicyclic [1,3,5]-triazinones from a diverse array of imines coupled with ethyl (pivaloyloxy)carbamate is reported. The preparation of [5,6]- and [6,6]-bicyclic heterocycles substituted with aryl, alkyl, and alkoxy groups demonstrated a broad reaction scope. The efficiency of this approach was further enhanced with the development of a three-component variant featuring in situ imine formation. X-ray crystallographic characterization of a rhodacycle formed by imidoyl C-H activation provides support for the proposed mechanism.