18886-65-2Relevant articles and documents
Evidence for Vinyl Nitrene Intermediates in the Thermal Rearrangement of 2H-Azirines into Indoles
Isomura, Kazuaki,Ayabe, Gen-Ichiro,Hatano, Sumiko,Taniguchi, Hiroshi
, p. 1252 - 1253 (1980)
Thermal racemization of optically active 3-methyl-2-phenyl-2H-azirine was found to be 2039 times faster than its rearrangement into 2-methylindole, which furnished firm evidence for the presence of vinyl nitrenes as intermediates.
Synthesis of 2,3-diaryl-2h-azirines via Cs2CO3-mediated cyclization of ketoxime acetates
Zhao, Mi-Na,Guan, Zheng-Hui
, p. 66 - 79 (2019/11/21)
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Rh(ii)-catalyzed cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines: Switchable reactivity of Rh-azavinylcarbene as [2C]- or aza-[3C]-synthon
Wang, Yuanhao,Lei, Xiaoqiang,Tang, Yefeng
supporting information, p. 4507 - 4510 (2015/03/18)
The Rh(ii)-catalyzed formal [3+2] and [3+3] cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines have been developed, which enable the efficient synthesis of polysubstituted 3-aminopyrroles and 1,2-dihydropyrazines, respectively. The reported [3+2] cycloaddition represents the first application of 1-sulfonyl 1,2,3-triazole as a [2C]-component in relevant cycloaddition reactions. This journal is
