18992-13-7Relevant articles and documents
Free Radical Pathways in the Nitrous Acid Deamination of α-Aminonitriles
Bunse, Michael,Joedicke, Dirk,Kirmse, Wolfgang
, p. 47 - 49 (1992)
Free radicals and carbocations are generated competitively in nitrous acid deamination reactions of α-aminonitriles: in the absence of added scavengers the radicals are trapped by NO2 and by NO.
Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions
Ilovaisky,Merkulova,Ogibin,Nikishin
, p. 1585 - 1592 (2007/10/03)
Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1- and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH2Cl2/H2O) produces geminal nitrohalides (35-85% yields), dinitro compounds (15-51%), nitronitriles (6-27%), and nitrosulfones (50-70%). The salts of secondary nitro compounds form the products of oxidative coupling with halide and phenylsulfinate anions under the undivided electrolysis conditions. In all other cases, divided electrolysis is required.
Reaction of Nitronate Salts with Cyanogen
Piotrowska, Hanna,Poplawska, Magdalena
, p. 517 - 520 (2007/10/02)
Nitronate salts react with cyanogen yielding mainly geminal nitronitriles.