190434-51-6

Basic information

• Product Name: (E)-2-(methoxyimino)-1-phenylpropan-1-one
• Synonyms: (E)-2-(methoxyimino)-1-phenylpropan-1-one
• CAS NO: 190434-51-6
• Molecular Weight: 177.203
• Mol File: 190434-51-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-2-(methoxyimino)-1-phenylpropan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(methoxyimino)-1-phenylpropan-1-one(190434-51-6)
• EPA Substance Registry System: (E)-2-(methoxyimino)-1-phenylpropan-1-one(190434-51-6)

Safety Data

• Hazardous Substances Data: 190434-51-6(Hazardous Substances Data)

Upstream product

• 4468-48-8 1-phenyl-1-cyanopropan-2-one 
• 873196-22-6 3-(methoxyimino)-2-phenylbutanenitrile 
• 17019-26-0 (E)-2-(hydroxyimino)-1-phenylpropan-1-one 
• 74-88-4 methyl iodide 
• 67-62-9 O-Methylhydroxylamin 
• 579-07-7 1-Phenylpropane-1,2-dione 

Downstream Products

• 579-07-7 1-Phenylpropane-1,2-dione 
• 37577-07-4 Norpseudoephedrine 
• 492-41-1 (1R,2S)-norephedrine 
• 196409-10-6 (-)-(R)-1-hydroxy-1-phenyl-2-propanone 2-(O-methyloxime) 
• 40421-52-1 (1R,2S)-1-phenylpropane-1,2-diol 

Relevant articles and documents

Synthesis of 1,2-diketones from β-keto nitriles via a protection-oxidative-decyanation-deprotection protocol

A variety of 1,2-diketones were prepared from -keto nitriles via a three-step protocol including the protection of the ketones with methoxyamine, oxidative decyanation, and microwave-assisted deprotection in the final step. This approach provides a novel and efficient access to a wide scope of symmetric and unsymmetric 1,2-diketones using molecular oxygen as the oxidant in the decyanation process. Georg Thieme Verlag Stuttgart - New York.