190840-84-7

Basic information

• Product Name: bis(furan-2-ylmethyl)(4-methoxybenzyl)amine
• CAS NO: 190840-84-7
• Molecular Weight: 297.354
• Mol File: 190840-84-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(furan-2-ylmethyl)(4-methoxybenzyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: bis(furan-2-ylmethyl)(4-methoxybenzyl)amine(190840-84-7)
• EPA Substance Registry System: bis(furan-2-ylmethyl)(4-methoxybenzyl)amine(190840-84-7)

Safety Data

• Hazardous Substances Data: 190840-84-7(Hazardous Substances Data)

Upstream product

• 18240-50-1 bis((furan-2-yl)methyl)amine 
• 2746-25-0 p-Methoxybenzyl bromide 
• 98-00-0 (2-furyl)methyl alcohol 
• 4437-18-7 2-bromomethylfuran 

Relevant articles and documents

An Expedient Route for the Stereoselective Construction of Bridged Polyheterocyclic Ring Systems Using the Tandem "Pincer" Diels-Alder Reaction

The tandem "pincer" Diels-Alder reaction, consisting of two consecutive [4 + 2] cycloadditions between two dienes and an acetylenic bis-dienophile, has been applied toward the rapid construction of bridged polyoxacyclic ring systems when furan derivatives are used as the diene components. The study has demonstrated the stereoselectivity (exo-exo adduct), the chemoselectivity ("pincer" vs "domino"), as well as the regioselectivity of the reaction. The reaction has been successfully applied to a variety of 2-substituted furans and tethered bis-furans in combination with mono-activated and diactivated dienophiles. The synthesis of unsymmetrical cycloadducts starting from the aza- and oxanorbornadiene-type intermediate has also been realized.